Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block

Zheng He; Cheng He; En Qing Gao; Zhe Ming Wang; Xiao Fan Yang; Chun Sheng Liao; Chun Hua Yan

doi:10.1021/ic026271n

Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block

Zheng He
, Cheng He
, En Qing Gao
, Zhe Ming Wang
, Xiao Fan Yang
, Chun Sheng Liao
, Chun Hua Yan^*

^*Corresponding author for this work

Peking University

Research output: Contribution to journal › Article › peer-review

106 Scopus citations

Abstract

One-dimensional lanthanide-transition heterometallic chains of squares, {LnNi₂L₃(HL)(DMF)₄(ClO₄) ₄·S}∞ (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and {LnNi₂L₄- (DMF)₄(ClO₄)₃·S}∞ (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L]⁺ and the Ln(III) ions, which act as the bridging units and nodes, respectively.

Original language	English
Pages (from-to)	2206-2208
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	7
DOIs	https://doi.org/10.1021/ic026271n
State	Published - 7 Apr 2003
Externally published	Yes

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@article{834869556d964396961764418f42273c,

title = "Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block",

abstract = "One-dimensional lanthanide-transition heterometallic chains of squares, \{LnNi2L3(HL)(DMF)4(ClO4) 4·S\}∞ (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and \{LnNi2L4- (DMF)4(ClO4)3·S\}∞ (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L]+ and the Ln(III) ions, which act as the bridging units and nodes, respectively.",

author = "Zheng He and Cheng He and Gao, \{En Qing\} and Wang, \{Zhe Ming\} and Yang, \{Xiao Fan\} and Liao, \{Chun Sheng\} and Yan, \{Chun Hua\}",

year = "2003",

month = apr,

day = "7",

doi = "10.1021/ic026271n",

language = "英语",

volume = "42",

pages = "2206--2208",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block

AU - He, Zheng

AU - He, Cheng

AU - Gao, En Qing

AU - Wang, Zhe Ming

AU - Yang, Xiao Fan

AU - Liao, Chun Sheng

AU - Yan, Chun Hua

PY - 2003/4/7

Y1 - 2003/4/7

N2 - One-dimensional lanthanide-transition heterometallic chains of squares, {LnNi2L3(HL)(DMF)4(ClO4) 4·S}∞ (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and {LnNi2L4- (DMF)4(ClO4)3·S}∞ (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L]+ and the Ln(III) ions, which act as the bridging units and nodes, respectively.

AB - One-dimensional lanthanide-transition heterometallic chains of squares, {LnNi2L3(HL)(DMF)4(ClO4) 4·S}∞ (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and {LnNi2L4- (DMF)4(ClO4)3·S}∞ (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L]+ and the Ln(III) ions, which act as the bridging units and nodes, respectively.

UR - https://www.scopus.com/pages/publications/0037425157

U2 - 10.1021/ic026271n

DO - 10.1021/ic026271n

M3 - 文章

AN - SCOPUS:0037425157

SN - 0020-1669

VL - 42

SP - 2206

EP - 2208

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block

Abstract

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