Kinetically controlled crystallization for synthesis of monodispersed coordination polymer nanocubes and their self-assembly to periodic arrangements

Ming Hu; Shinsuke Ishihara; Katsuhiko Ariga; Masataka Imura; Yusuke Yamauchi

doi:10.1002/chem.201203138

Kinetically controlled crystallization for synthesis of monodispersed coordination polymer nanocubes and their self-assembly to periodic arrangements

Ming Hu
, Shinsuke Ishihara
, Katsuhiko Ariga
, Masataka Imura
, Yusuke Yamauchi^*

^*Corresponding author for this work

National Institute for Materials Science Tsukuba
Waseda University
Japan Science and Technology Agency

Research output: Contribution to journal › Article › peer-review

131 Scopus citations

Abstract

Under control: A new concept for synthesizing monodispersed coordination polymer (CP) nanoparticles is established. By utilizing a chelating agent that is coordinated to the metal ions, the subsequent coordination process between metal ions and ligands is controllable (see figure). The obtained nanocubes with uniform sizes can be self-assembled into periodically ordered arrangements. This phenomenon is useful for sensing applications, such as those with responsive photonic crystals.

Original language	English
Pages (from-to)	1882-1885
Number of pages	4
Journal	Chemistry - A European Journal
Volume	19
Issue number	6
DOIs	https://doi.org/10.1002/chem.201203138
State	Published - 4 Feb 2013
Externally published	Yes

Keywords

coordination polymers
crystallization
nanoporous materials
self-assembly

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10.1002/chem.201203138

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abstract = "Under control: A new concept for synthesizing monodispersed coordination polymer (CP) nanoparticles is established. By utilizing a chelating agent that is coordinated to the metal ions, the subsequent coordination process between metal ions and ligands is controllable (see figure). The obtained nanocubes with uniform sizes can be self-assembled into periodically ordered arrangements. This phenomenon is useful for sensing applications, such as those with responsive photonic crystals.",

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AU - Hu, Ming

AU - Ishihara, Shinsuke

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AU - Imura, Masataka

AU - Yamauchi, Yusuke

PY - 2013/2/4

Y1 - 2013/2/4

N2 - Under control: A new concept for synthesizing monodispersed coordination polymer (CP) nanoparticles is established. By utilizing a chelating agent that is coordinated to the metal ions, the subsequent coordination process between metal ions and ligands is controllable (see figure). The obtained nanocubes with uniform sizes can be self-assembled into periodically ordered arrangements. This phenomenon is useful for sensing applications, such as those with responsive photonic crystals.

AB - Under control: A new concept for synthesizing monodispersed coordination polymer (CP) nanoparticles is established. By utilizing a chelating agent that is coordinated to the metal ions, the subsequent coordination process between metal ions and ligands is controllable (see figure). The obtained nanocubes with uniform sizes can be self-assembled into periodically ordered arrangements. This phenomenon is useful for sensing applications, such as those with responsive photonic crystals.

KW - coordination polymers

KW - crystallization

KW - nanoporous materials

KW - self-assembly

UR - https://www.scopus.com/pages/publications/84873305122

U2 - 10.1002/chem.201203138

DO - 10.1002/chem.201203138

M3 - 文章

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JO - Chemistry - A European Journal

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Kinetically controlled crystallization for synthesis of monodispersed coordination polymer nanocubes and their self-assembly to periodic arrangements

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Keywords

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