Iron-catalyzed, microwave-promoted, one-pot synthesis of 9-substituted xanthenes by a cascade benzylation-cyclization process

Xiaobing Xu; Xiaolei Xu; Hongfeng Li; Xin Xie; Yanzhong Li

doi:10.1021/ol902489a

Iron-catalyzed, microwave-promoted, one-pot synthesis of 9-substituted xanthenes by a cascade benzylation-cyclization process

Xiaobing Xu
, Xiaolei Xu
, Hongfeng Li
, Xin Xie
, Yanzhong Li^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

"Chemical Equation Presented" An efficient iron-catalyzed, microwave-promoted cascade benzylation-cyclization of phenols is reported. Benzyl acetates, benzyl bromides, and benzyl carbonates are suitable benzylating reagents. The reactions proceed to afford both 9-aryl and 9-alkyl xanthene derivatives in good to high yields using FeCI3 as the catalyst under MW irradiation conditions

Original language	English
Pages (from-to)	100-103
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	1
DOIs	https://doi.org/10.1021/ol902489a
State	Published - 1 Jan 2010

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10.1021/ol902489a

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title = "Iron-catalyzed, microwave-promoted, one-pot synthesis of 9-substituted xanthenes by a cascade benzylation-cyclization process",

abstract = "{"}Chemical Equation Presented{"} An efficient iron-catalyzed, microwave-promoted cascade benzylation-cyclization of phenols is reported. Benzyl acetates, benzyl bromides, and benzyl carbonates are suitable benzylating reagents. The reactions proceed to afford both 9-aryl and 9-alkyl xanthene derivatives in good to high yields using FeCI3 as the catalyst under MW irradiation conditions",

author = "Xiaobing Xu and Xiaolei Xu and Hongfeng Li and Xin Xie and Yanzhong Li",

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T1 - Iron-catalyzed, microwave-promoted, one-pot synthesis of 9-substituted xanthenes by a cascade benzylation-cyclization process

AU - Xu, Xiaobing

AU - Xu, Xiaolei

AU - Li, Hongfeng

AU - Xie, Xin

AU - Li, Yanzhong

PY - 2010/1/1

Y1 - 2010/1/1

N2 - "Chemical Equation Presented" An efficient iron-catalyzed, microwave-promoted cascade benzylation-cyclization of phenols is reported. Benzyl acetates, benzyl bromides, and benzyl carbonates are suitable benzylating reagents. The reactions proceed to afford both 9-aryl and 9-alkyl xanthene derivatives in good to high yields using FeCI3 as the catalyst under MW irradiation conditions

AB - "Chemical Equation Presented" An efficient iron-catalyzed, microwave-promoted cascade benzylation-cyclization of phenols is reported. Benzyl acetates, benzyl bromides, and benzyl carbonates are suitable benzylating reagents. The reactions proceed to afford both 9-aryl and 9-alkyl xanthene derivatives in good to high yields using FeCI3 as the catalyst under MW irradiation conditions

UR - https://www.scopus.com/pages/publications/73949112663

U2 - 10.1021/ol902489a

DO - 10.1021/ol902489a

M3 - 文章

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AN - SCOPUS:73949112663

SN - 1523-7060

VL - 12

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EP - 103

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Iron-catalyzed, microwave-promoted, one-pot synthesis of 9-substituted xanthenes by a cascade benzylation-cyclization process

Abstract

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