Iron-catalysed chemo-and: Ortho-selective C-H bond functionalization of phenols with α-Aryl-α-diazoacetates

Zhunzhun Yu; Guanghui Li; Junliang Zhang; Lu Liu

doi:10.1039/d1qo00276g

Iron-catalysed chemo-and: Ortho-selective C-H bond functionalization of phenols with α-Aryl-α-diazoacetates

Zhunzhun Yu
, Guanghui Li
, Junliang Zhang
, Lu Liu

School of Chemistry and Molecular Engineering

East China Normal University
Fudan University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Herein we present a novel iron-catalyzed chemo-and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.

Original language	English
Pages (from-to)	3770-3775
Number of pages	6
Journal	Organic Chemistry Frontiers
Volume	8
Issue number	14
DOIs	https://doi.org/10.1039/d1qo00276g
State	Published - 21 Jul 2021

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title = "Iron-catalysed chemo-and: Ortho-selective C-H bond functionalization of phenols with α-Aryl-α-diazoacetates",

abstract = "Herein we present a novel iron-catalyzed chemo-and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.",

author = "Zhunzhun Yu and Guanghui Li and Junliang Zhang and Lu Liu",

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T1 - Iron-catalysed chemo-and

T2 - Ortho-selective C-H bond functionalization of phenols with α-Aryl-α-diazoacetates

AU - Yu, Zhunzhun

AU - Li, Guanghui

AU - Zhang, Junliang

AU - Liu, Lu

PY - 2021/7/21

Y1 - 2021/7/21

N2 - Herein we present a novel iron-catalyzed chemo-and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.

AB - Herein we present a novel iron-catalyzed chemo-and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.

UR - https://www.scopus.com/pages/publications/85109314457

U2 - 10.1039/d1qo00276g

DO - 10.1039/d1qo00276g

M3 - 文章

AN - SCOPUS:85109314457

SN - 2052-4110

VL - 8

SP - 3770

EP - 3775

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 14

ER -

Iron-catalysed chemo-and: Ortho-selective C-H bond functionalization of phenols with α-Aryl-α-diazoacetates

Abstract

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