Ionic conductor armored Li3V2(PO4)3: a robust electrode for lithium capture via capacitive desalination

Lanlan Han; Jiaqi Liu; Ruoxing Wang; Tianyi Wang; Chengyin Wang; Xingtao Xu; Likun Pan; Jiabao Li

doi:10.1039/d5cc03535j

Ionic conductor armored Li₃V₂(PO₄)₃: a robust electrode for lithium capture via capacitive desalination

Lanlan Han
, Jiaqi Liu
, Ruoxing Wang
, Tianyi Wang^*
, Chengyin Wang
, Xingtao Xu^*
, Likun Pan^*
, Jiabao Li^*

^*Corresponding author for this work

School of Physics and Electronic Science

Yangzhou University
Zhejiang Ocean University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The poor ionic conductivity and sluggish interfacial kinetics of Li₃V₂(PO₄)₃ (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li₃PO₄ coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li⁺ adsorption capacity of 6.48 mmol g⁻¹ within 150 mg L⁻¹ LiCl at 1.2 V with excellent selectivity in simulated brines.

Original language	English
Pages (from-to)	14141-14144
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	74
DOIs	https://doi.org/10.1039/d5cc03535j
State	Published - 11 Sep 2025

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title = "Ionic conductor armored Li3V2(PO4)3: a robust electrode for lithium capture via capacitive desalination",

abstract = "The poor ionic conductivity and sluggish interfacial kinetics of Li3V2(PO4)3 (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li3PO4 coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li+ adsorption capacity of 6.48 mmol g−1 within 150 mg L−1 LiCl at 1.2 V with excellent selectivity in simulated brines.",

author = "Lanlan Han and Jiaqi Liu and Ruoxing Wang and Tianyi Wang and Chengyin Wang and Xingtao Xu and Likun Pan and Jiabao Li",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

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doi = "10.1039/d5cc03535j",

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TY - JOUR

T1 - Ionic conductor armored Li3V2(PO4)3

T2 - a robust electrode for lithium capture via capacitive desalination

AU - Han, Lanlan

AU - Liu, Jiaqi

AU - Wang, Ruoxing

AU - Wang, Tianyi

AU - Wang, Chengyin

AU - Xu, Xingtao

AU - Pan, Likun

AU - Li, Jiabao

PY - 2025/9/11

Y1 - 2025/9/11

N2 - The poor ionic conductivity and sluggish interfacial kinetics of Li3V2(PO4)3 (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li3PO4 coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li+ adsorption capacity of 6.48 mmol g−1 within 150 mg L−1 LiCl at 1.2 V with excellent selectivity in simulated brines.

AB - The poor ionic conductivity and sluggish interfacial kinetics of Li3V2(PO4)3 (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li3PO4 coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li+ adsorption capacity of 6.48 mmol g−1 within 150 mg L−1 LiCl at 1.2 V with excellent selectivity in simulated brines.

UR - https://www.scopus.com/pages/publications/105015625080

U2 - 10.1039/d5cc03535j

DO - 10.1039/d5cc03535j

M3 - 文章

C2 - 40827863

AN - SCOPUS:105015625080

SN - 1359-7345

VL - 61

SP - 14141

EP - 14144

JO - Chemical Communications

JF - Chemical Communications

IS - 74

ER -

Ionic conductor armored Li₃V₂(PO₄)₃: a robust electrode for lithium capture via capacitive desalination

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