Ion-pair effect of phosphino-imidazolium salts on Rh(III)-complex catalyzed hydroformylation of 1-octene in water suspension

Sheng Jie Chen; Yong Yong Wang; Yong Qi Li; Xiao Li Zhao; Ye Liu

doi:10.1016/j.catcom.2014.02.017

Ion-pair effect of phosphino-imidazolium salts on Rh(III)-complex catalyzed hydroformylation of 1-octene in water suspension

Sheng Jie Chen, Yong Yong Wang, Yong Qi Li, Xiao Li Zhao, Ye Liu

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A series of phosphino-imidazolium salts (1-4), which are composed of the phosphine-incorporated imidazolium cations and the corresponding counter-anions of PF₆^-, TfO^-, and BF₄^-, are used in Rh-catalyzed hydroformylation. It was found that when the ionic Rh(III)-complex (1A, [Rh^IIICl₄(L)₂]PF ₆, L = 1-butyl-2-diphenylphosphino-3-methylimidazolium) was used as the pre-catalyst for hydroformylation of 1-octene, its inert catalytic activity could be efficiently tailored by the ion-pair synergetic effect of ligand 1-4 in water suspension. The single crystal structures of 1, 2, and 4 indicate that the hydrogen bonding network is developed between the cation and anion of ion-pairs 1 and 4, but is completely non-inexistent in 2.

Original language	English
Pages (from-to)	5-8
Number of pages	4
Journal	Catalysis Communications
Volume	50
DOIs	https://doi.org/10.1016/j.catcom.2014.02.017
State	Published - 5 May 2014

Keywords

1-Octene
Hydroformylation
Imidazolium salts
Phosphines
Rhodium complexes

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@article{3c0ecf1a0d584c149c820c0fc6acc8d7,

title = "Ion-pair effect of phosphino-imidazolium salts on Rh(III)-complex catalyzed hydroformylation of 1-octene in water suspension",

abstract = "A series of phosphino-imidazolium salts (1-4), which are composed of the phosphine-incorporated imidazolium cations and the corresponding counter-anions of PF6-, TfO-, and BF4-, are used in Rh-catalyzed hydroformylation. It was found that when the ionic Rh(III)-complex (1A, [RhIIICl4(L)2]PF 6, L = 1-butyl-2-diphenylphosphino-3-methylimidazolium) was used as the pre-catalyst for hydroformylation of 1-octene, its inert catalytic activity could be efficiently tailored by the ion-pair synergetic effect of ligand 1-4 in water suspension. The single crystal structures of 1, 2, and 4 indicate that the hydrogen bonding network is developed between the cation and anion of ion-pairs 1 and 4, but is completely non-inexistent in 2.",

keywords = "1-Octene, Hydroformylation, Imidazolium salts, Phosphines, Rhodium complexes",

author = "Chen, \{Sheng Jie\} and Wang, \{Yong Yong\} and Li, \{Yong Qi\} and Zhao, \{Xiao Li\} and Ye Liu",

year = "2014",

month = may,

day = "5",

doi = "10.1016/j.catcom.2014.02.017",

language = "英语",

volume = "50",

pages = "5--8",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Ion-pair effect of phosphino-imidazolium salts on Rh(III)-complex catalyzed hydroformylation of 1-octene in water suspension

AU - Chen, Sheng Jie

AU - Wang, Yong Yong

AU - Li, Yong Qi

AU - Zhao, Xiao Li

AU - Liu, Ye

PY - 2014/5/5

Y1 - 2014/5/5

N2 - A series of phosphino-imidazolium salts (1-4), which are composed of the phosphine-incorporated imidazolium cations and the corresponding counter-anions of PF6-, TfO-, and BF4-, are used in Rh-catalyzed hydroformylation. It was found that when the ionic Rh(III)-complex (1A, [RhIIICl4(L)2]PF 6, L = 1-butyl-2-diphenylphosphino-3-methylimidazolium) was used as the pre-catalyst for hydroformylation of 1-octene, its inert catalytic activity could be efficiently tailored by the ion-pair synergetic effect of ligand 1-4 in water suspension. The single crystal structures of 1, 2, and 4 indicate that the hydrogen bonding network is developed between the cation and anion of ion-pairs 1 and 4, but is completely non-inexistent in 2.

AB - A series of phosphino-imidazolium salts (1-4), which are composed of the phosphine-incorporated imidazolium cations and the corresponding counter-anions of PF6-, TfO-, and BF4-, are used in Rh-catalyzed hydroformylation. It was found that when the ionic Rh(III)-complex (1A, [RhIIICl4(L)2]PF 6, L = 1-butyl-2-diphenylphosphino-3-methylimidazolium) was used as the pre-catalyst for hydroformylation of 1-octene, its inert catalytic activity could be efficiently tailored by the ion-pair synergetic effect of ligand 1-4 in water suspension. The single crystal structures of 1, 2, and 4 indicate that the hydrogen bonding network is developed between the cation and anion of ion-pairs 1 and 4, but is completely non-inexistent in 2.

KW - 1-Octene

KW - Hydroformylation

KW - Imidazolium salts

KW - Phosphines

KW - Rhodium complexes

UR - https://www.scopus.com/pages/publications/84896343457

U2 - 10.1016/j.catcom.2014.02.017

DO - 10.1016/j.catcom.2014.02.017

M3 - 文章

AN - SCOPUS:84896343457

SN - 1566-7367

VL - 50

SP - 5

EP - 8

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Ion-pair effect of phosphino-imidazolium salts on Rh(III)-complex catalyzed hydroformylation of 1-octene in water suspension

Abstract

Keywords

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