TY - JOUR
T1 - Intrinsic Features of an Ideal Glass
AU - Sun, Deyan
AU - Shang, Cheng
AU - Liu, Zhipan
AU - Gong, Xingao
N1 - Publisher Copyright:
© 2017 Chinese Physical Society and IOP Publishing Ltd.
PY - 2017
Y1 - 2017
N2 - In order to understand the long-standing problem of the nature of glass states, we perform intensive simulations on the thermodynamic properties and potential energy surface of an ideal glass. It is found that the atoms of an ideal glass manifest cooperative diffusion, and show clearly different behavior from the liquid state. By determining the potential energy surface, we demonstrate that the glass state has a flat potential landscape, which is the critical intrinsic feature of ideal glasses. When this potential region is accessible through any thermal or kinetic process, the glass state can be formed and a glass transition will occur, regardless of any special structural character. With this picture, the glass transition can be interpreted by the emergence of configurational entropies, as a consequence of flat potential landscapes.
AB - In order to understand the long-standing problem of the nature of glass states, we perform intensive simulations on the thermodynamic properties and potential energy surface of an ideal glass. It is found that the atoms of an ideal glass manifest cooperative diffusion, and show clearly different behavior from the liquid state. By determining the potential energy surface, we demonstrate that the glass state has a flat potential landscape, which is the critical intrinsic feature of ideal glasses. When this potential region is accessible through any thermal or kinetic process, the glass state can be formed and a glass transition will occur, regardless of any special structural character. With this picture, the glass transition can be interpreted by the emergence of configurational entropies, as a consequence of flat potential landscapes.
UR - https://www.scopus.com/pages/publications/85035199819
U2 - 10.1088/0256-307X/34/2/026402
DO - 10.1088/0256-307X/34/2/026402
M3 - 文章
AN - SCOPUS:85035199819
SN - 0256-307X
VL - 34
JO - Chinese Physics Letters
JF - Chinese Physics Letters
IS - 2
M1 - 026402
ER -