Intrinsic Features of an Ideal Glass

Deyan Sun, Cheng Shang, Zhipan Liu, Xingao Gong*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

In order to understand the long-standing problem of the nature of glass states, we perform intensive simulations on the thermodynamic properties and potential energy surface of an ideal glass. It is found that the atoms of an ideal glass manifest cooperative diffusion, and show clearly different behavior from the liquid state. By determining the potential energy surface, we demonstrate that the glass state has a flat potential landscape, which is the critical intrinsic feature of ideal glasses. When this potential region is accessible through any thermal or kinetic process, the glass state can be formed and a glass transition will occur, regardless of any special structural character. With this picture, the glass transition can be interpreted by the emergence of configurational entropies, as a consequence of flat potential landscapes.

Original languageEnglish
Article number026402
JournalChinese Physics Letters
Volume34
Issue number2
DOIs
StatePublished - 2017

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