Intense infrared luminescence in transparent glass-ceramics containing β-Ga2O3:Ni2+ Nanocrystals

Shifeng Zhou; Gaofeng Feng; Botao Wu; Nan Jiang; Shiqing Xu; Jianrong Qiu

doi:10.1021/jp068370i

Intense infrared luminescence in transparent glass-ceramics containing β-Ga₂O₃:Ni²⁺ Nanocrystals

Shifeng Zhou
, Gaofeng Feng
, Botao Wu
, Nan Jiang
, Shiqing Xu
, Jianrong Qiu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

Transparent glass-ceramics containing β-Ga₂O ₃:Ni²⁺ nanocrystals were synthesized and characterized by X-ray diffraction, transmission electron microscopy, and electron energy loss spectroscopy. Intense broad-band luminescence centering at 1200 nm was observed when the sample was excited by a diode laser at 980 nm. The room-temperature fluorescent lifetime was 665 μs, which is longer than the Ni ²⁺-doped ZnAl₂O₄ and LiGa₅O ₈ glass-ceramics and is also comparable to the Ni²⁺-doped LiGa₅O₈ single crystal, The intense infrared luminescence with long fluorescent lifetime may be ascribed to the high crystal field hold by Ni²⁺ and the moderate lattice phonon energy of β-Ga ₂O₃. The excellent optical properties of this novel material indicate that it might be a promising candidate for broad-band amplifiers and room-temperature tunable lasers.

Original language	English
Pages (from-to)	7335-7338
Number of pages	4
Journal	Journal of Physical Chemistry C
Volume	111
Issue number	20
DOIs	https://doi.org/10.1021/jp068370i
State	Published - 24 May 2007
Externally published	Yes

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title = "Intense infrared luminescence in transparent glass-ceramics containing β-Ga2O3:Ni2+ Nanocrystals",

abstract = "Transparent glass-ceramics containing β-Ga2O 3:Ni2+ nanocrystals were synthesized and characterized by X-ray diffraction, transmission electron microscopy, and electron energy loss spectroscopy. Intense broad-band luminescence centering at 1200 nm was observed when the sample was excited by a diode laser at 980 nm. The room-temperature fluorescent lifetime was 665 μs, which is longer than the Ni 2+-doped ZnAl2O4 and LiGa5O 8 glass-ceramics and is also comparable to the Ni2+-doped LiGa5O8 single crystal, The intense infrared luminescence with long fluorescent lifetime may be ascribed to the high crystal field hold by Ni2+ and the moderate lattice phonon energy of β-Ga 2O3. The excellent optical properties of this novel material indicate that it might be a promising candidate for broad-band amplifiers and room-temperature tunable lasers.",

author = "Shifeng Zhou and Gaofeng Feng and Botao Wu and Nan Jiang and Shiqing Xu and Jianrong Qiu",

year = "2007",

month = may,

day = "24",

doi = "10.1021/jp068370i",

language = "英语",

volume = "111",

pages = "7335--7338",

journal = "Journal of Physical Chemistry C",

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TY - JOUR

T1 - Intense infrared luminescence in transparent glass-ceramics containing β-Ga2O3:Ni2+ Nanocrystals

AU - Zhou, Shifeng

AU - Feng, Gaofeng

AU - Wu, Botao

AU - Jiang, Nan

AU - Xu, Shiqing

AU - Qiu, Jianrong

PY - 2007/5/24

Y1 - 2007/5/24

N2 - Transparent glass-ceramics containing β-Ga2O 3:Ni2+ nanocrystals were synthesized and characterized by X-ray diffraction, transmission electron microscopy, and electron energy loss spectroscopy. Intense broad-band luminescence centering at 1200 nm was observed when the sample was excited by a diode laser at 980 nm. The room-temperature fluorescent lifetime was 665 μs, which is longer than the Ni 2+-doped ZnAl2O4 and LiGa5O 8 glass-ceramics and is also comparable to the Ni2+-doped LiGa5O8 single crystal, The intense infrared luminescence with long fluorescent lifetime may be ascribed to the high crystal field hold by Ni2+ and the moderate lattice phonon energy of β-Ga 2O3. The excellent optical properties of this novel material indicate that it might be a promising candidate for broad-band amplifiers and room-temperature tunable lasers.

AB - Transparent glass-ceramics containing β-Ga2O 3:Ni2+ nanocrystals were synthesized and characterized by X-ray diffraction, transmission electron microscopy, and electron energy loss spectroscopy. Intense broad-band luminescence centering at 1200 nm was observed when the sample was excited by a diode laser at 980 nm. The room-temperature fluorescent lifetime was 665 μs, which is longer than the Ni 2+-doped ZnAl2O4 and LiGa5O 8 glass-ceramics and is also comparable to the Ni2+-doped LiGa5O8 single crystal, The intense infrared luminescence with long fluorescent lifetime may be ascribed to the high crystal field hold by Ni2+ and the moderate lattice phonon energy of β-Ga 2O3. The excellent optical properties of this novel material indicate that it might be a promising candidate for broad-band amplifiers and room-temperature tunable lasers.

UR - https://www.scopus.com/pages/publications/34250343756

U2 - 10.1021/jp068370i

DO - 10.1021/jp068370i

M3 - 文章

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SN - 1932-7447

VL - 111

SP - 7335

EP - 7338

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 20

ER -

Intense infrared luminescence in transparent glass-ceramics containing β-Ga₂O₃:Ni²⁺ Nanocrystals

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