Indirect high-resolution detection for quadrupolar spin-3/2 nuclei in dipolar HMQC solid-state NMR experiments

Julien Trébosc; Olivier Lafon; Bingwen Hu; Jean Paul Amoureux

doi:10.1016/j.cplett.2010.07.037

Indirect high-resolution detection for quadrupolar spin-3/2 nuclei in dipolar HMQC solid-state NMR experiments

Julien Trébosc, Olivier Lafon, Bingwen Hu, Jean Paul Amoureux

School of Physics and Electronic Science

Université de Lille

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

We present a new kind of NMR pulse sequences to observe heteronuclear correlation (HETCOR) specifically between spin-1/2 and spin-3/2 nuclei with isotropic resolution on the quadrupolar channel. These methods, called HMQC-ST, feature a STMAS filter during the evolution period of the HMQC scheme. Compared to existing HETCOR techniques involving quadrupolar nuclei, the HMQC-ST combines high-resolution and high efficiency and allows indirect detection of spin-3/2 nuclei via sensitive nuclei. We study analytically and using simulations how through-bond and through-space HMQC-ST perform compared to regular HMQC sequence. HMQC-ST potential is demonstrated experimentally by recording through-space HETCOR 2D spectra of Na₂HPO₄ and NaH ₂PO₄.

Original language	English
Pages (from-to)	201-207
Number of pages	7
Journal	Chemical Physics Letters
Volume	496
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2010.07.037
State	Published - 20 Aug 2010

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title = "Indirect high-resolution detection for quadrupolar spin-3/2 nuclei in dipolar HMQC solid-state NMR experiments",

abstract = "We present a new kind of NMR pulse sequences to observe heteronuclear correlation (HETCOR) specifically between spin-1/2 and spin-3/2 nuclei with isotropic resolution on the quadrupolar channel. These methods, called HMQC-ST, feature a STMAS filter during the evolution period of the HMQC scheme. Compared to existing HETCOR techniques involving quadrupolar nuclei, the HMQC-ST combines high-resolution and high efficiency and allows indirect detection of spin-3/2 nuclei via sensitive nuclei. We study analytically and using simulations how through-bond and through-space HMQC-ST perform compared to regular HMQC sequence. HMQC-ST potential is demonstrated experimentally by recording through-space HETCOR 2D spectra of Na2HPO4 and NaH 2PO4.",

author = "Julien Tr{\'e}bosc and Olivier Lafon and Bingwen Hu and Amoureux, \{Jean Paul\}",

year = "2010",

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doi = "10.1016/j.cplett.2010.07.037",

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TY - JOUR

T1 - Indirect high-resolution detection for quadrupolar spin-3/2 nuclei in dipolar HMQC solid-state NMR experiments

AU - Trébosc, Julien

AU - Lafon, Olivier

AU - Hu, Bingwen

AU - Amoureux, Jean Paul

PY - 2010/8/20

Y1 - 2010/8/20

N2 - We present a new kind of NMR pulse sequences to observe heteronuclear correlation (HETCOR) specifically between spin-1/2 and spin-3/2 nuclei with isotropic resolution on the quadrupolar channel. These methods, called HMQC-ST, feature a STMAS filter during the evolution period of the HMQC scheme. Compared to existing HETCOR techniques involving quadrupolar nuclei, the HMQC-ST combines high-resolution and high efficiency and allows indirect detection of spin-3/2 nuclei via sensitive nuclei. We study analytically and using simulations how through-bond and through-space HMQC-ST perform compared to regular HMQC sequence. HMQC-ST potential is demonstrated experimentally by recording through-space HETCOR 2D spectra of Na2HPO4 and NaH 2PO4.

AB - We present a new kind of NMR pulse sequences to observe heteronuclear correlation (HETCOR) specifically between spin-1/2 and spin-3/2 nuclei with isotropic resolution on the quadrupolar channel. These methods, called HMQC-ST, feature a STMAS filter during the evolution period of the HMQC scheme. Compared to existing HETCOR techniques involving quadrupolar nuclei, the HMQC-ST combines high-resolution and high efficiency and allows indirect detection of spin-3/2 nuclei via sensitive nuclei. We study analytically and using simulations how through-bond and through-space HMQC-ST perform compared to regular HMQC sequence. HMQC-ST potential is demonstrated experimentally by recording through-space HETCOR 2D spectra of Na2HPO4 and NaH 2PO4.

UR - https://www.scopus.com/pages/publications/77955560496

U2 - 10.1016/j.cplett.2010.07.037

DO - 10.1016/j.cplett.2010.07.037

M3 - 文章

AN - SCOPUS:77955560496

SN - 0009-2614

VL - 496

SP - 201

EP - 207

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Indirect high-resolution detection for quadrupolar spin-3/2 nuclei in dipolar HMQC solid-state NMR experiments

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