Abstract
The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4′-dipyridyl)- 9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120° tecton 2 is also discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 6644-6647 |
| Number of pages | 4 |
| Journal | Journal of Organic Chemistry |
| Volume | 71 |
| Issue number | 17 |
| DOIs | |
| State | Published - 18 Aug 2006 |
| Externally published | Yes |