Incorporation of 2,6-di(4,4′-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly

Hai Bo Yang, Neeladri Das, Feihe Huang, Adam M. Hawkridge, David D. Díaz, Atta M. Arif, M. G. Finn, David C. Muddiman, Peter J. Stang

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28 Scopus citations

Abstract

The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4′-dipyridyl)- 9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120° tecton 2 is also discussed.

Original languageEnglish
Pages (from-to)6644-6647
Number of pages4
JournalJournal of Organic Chemistry
Volume71
Issue number17
DOIs
StatePublished - 18 Aug 2006
Externally publishedYes

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