Incorporation of 2,6-di(4,4′-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly

Hai Bo Yang; Neeladri Das; Feihe Huang; Adam M. Hawkridge; David D. Díaz; Atta M. Arif; M. G. Finn; David C. Muddiman; Peter J. Stang

doi:10.1021/jo0608117

Incorporation of 2,6-di(4,4′-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly

Hai Bo Yang
, Neeladri Das
, Feihe Huang
, Adam M. Hawkridge
, David D. Díaz
, Atta M. Arif
, M. G. Finn
, David C. Muddiman
, Peter J. Stang^*

^*Corresponding author for this work

University of Utah
North Carolina State University
Scripps Research Institute

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4′-dipyridyl)- 9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (¹H and ³¹P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120° tecton 2 is also discussed.

Original language	English
Pages (from-to)	6644-6647
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	71
Issue number	17
DOIs	https://doi.org/10.1021/jo0608117
State	Published - 18 Aug 2006
Externally published	Yes

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title = "Incorporation of 2,6-di(4,4′-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly",

abstract = "The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90\%). These assemblies have 2,6-di(4,4′-dipyridyl)- 9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120° tecton 2 is also discussed.",

author = "Yang, \{Hai Bo\} and Neeladri Das and Feihe Huang and Hawkridge, \{Adam M.\} and D{\'i}az, \{David D.\} and Arif, \{Atta M.\} and Finn, \{M. G.\} and Muddiman, \{David C.\} and Stang, \{Peter J.\}",

year = "2006",

month = aug,

day = "18",

doi = "10.1021/jo0608117",

language = "英语",

volume = "71",

pages = "6644--6647",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Incorporation of 2,6-di(4,4′-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly

AU - Yang, Hai Bo

AU - Das, Neeladri

AU - Huang, Feihe

AU - Hawkridge, Adam M.

AU - Díaz, David D.

AU - Arif, Atta M.

AU - Finn, M. G.

AU - Muddiman, David C.

AU - Stang, Peter J.

PY - 2006/8/18

Y1 - 2006/8/18

N2 - The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4′-dipyridyl)- 9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120° tecton 2 is also discussed.

AB - The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4′-dipyridyl)- 9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120° tecton 2 is also discussed.

UR - https://www.scopus.com/pages/publications/33747406967

U2 - 10.1021/jo0608117

DO - 10.1021/jo0608117

M3 - 文章

C2 - 16901162

AN - SCOPUS:33747406967

SN - 0022-3263

VL - 71

SP - 6644

EP - 6647

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 17

ER -

Incorporation of 2,6-di(4,4′-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly

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