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Incorporating a flexible crown ether into neutral discrete self-assemblies driven by metal coordination

  • Feihe Huang*
  • , Hai Bo Yang
  • , Neeladri Das
  • , Umamageswaran Maran
  • , Atta M. Arif
  • , Harry W. Gibson
  • , Peter J. Stang
  • *Corresponding author for this work
  • Zhejiang University
  • University of Utah
  • Virginia Polytechnic Institute and State University

Research output: Contribution to journalArticlepeer-review

Abstract

Driven by metal coordination, a flexible crown ether was self-assembled into neutral discrete complexes with two organoplatinum acceptors. Specifically, a [1+1]-assembled structure was separated from self-assemblies with different stoichiometries by vapor diffusion of acetone into their dichloromethane solution. The formation of these crown ether-incorporated self-assemblies was confirmed by NMR, elemental analysis, and X-ray single-crystal analysis.

Original languageEnglish
Pages (from-to)6623-6625
Number of pages3
JournalJournal of Organic Chemistry
Volume71
Issue number17
DOIs
StatePublished - 18 Aug 2006
Externally publishedYes

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