Impetus for solvothermal synthesis technique: Synthesis and structure of a novel 1-D borophosphate using ionic liquid as medium

Hengzhen Shi; Yongkui Shan; Mingyuan He; Yuyan Liu

doi:10.1016/S0022-4596(03)00340-2

Impetus for solvothermal synthesis technique: Synthesis and structure of a novel 1-D borophosphate using ionic liquid as medium

Hengzhen Shi
, Yongkui Shan^*
, Mingyuan He
, Yuyan Liu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A novel borophosphate compound has been synthesized under solvothermal conditions using ionic liquid as a medium and structurally characterized by single-crystal X-ray diffractions. The compound crystallizes in the monoclinic, space group P2(1)/n, a=8.089(8)Å, b=13.977(12)Å, c=8.441(8)Å, β=112.517(11)°, Z=2, V=881.7(14)Å³, R ₁=0.03, wR₂=0.079 and S=1.01. Its structure consists of a 1-D straight chain that is built of the alternative linkage of mutually perpendicular four-member rings. Other characterizations by IR and thermal and elemental analyses are also described.

Original language	English
Pages (from-to)	33-36
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	176
Issue number	1
DOIs	https://doi.org/10.1016/S0022-4596(03)00340-2
State	Published - 15 Nov 2003

Keywords

Borophosphate
Characterization
Ionic liquid
Medium
Single crystal
Solvothermal technique
Straight chain
Structure
Tetrahedra
X-ray diffraction

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10.1016/S0022-4596(03)00340-2

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title = "Impetus for solvothermal synthesis technique: Synthesis and structure of a novel 1-D borophosphate using ionic liquid as medium",

abstract = "A novel borophosphate compound has been synthesized under solvothermal conditions using ionic liquid as a medium and structurally characterized by single-crystal X-ray diffractions. The compound crystallizes in the monoclinic, space group P2(1)/n, a=8.089(8){\AA}, b=13.977(12){\AA}, c=8.441(8){\AA}, β=112.517(11)°, Z=2, V=881.7(14){\AA}3, R 1=0.03, wR2=0.079 and S=1.01. Its structure consists of a 1-D straight chain that is built of the alternative linkage of mutually perpendicular four-member rings. Other characterizations by IR and thermal and elemental analyses are also described.",

keywords = "Borophosphate, Characterization, Ionic liquid, Medium, Single crystal, Solvothermal technique, Straight chain, Structure, Tetrahedra, X-ray diffraction",

author = "Hengzhen Shi and Yongkui Shan and Mingyuan He and Yuyan Liu",

year = "2003",

month = nov,

day = "15",

doi = "10.1016/S0022-4596(03)00340-2",

language = "英语",

volume = "176",

pages = "33--36",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "1",

}

TY - JOUR

T1 - Impetus for solvothermal synthesis technique

T2 - Synthesis and structure of a novel 1-D borophosphate using ionic liquid as medium

AU - Shi, Hengzhen

AU - Shan, Yongkui

AU - He, Mingyuan

AU - Liu, Yuyan

PY - 2003/11/15

Y1 - 2003/11/15

N2 - A novel borophosphate compound has been synthesized under solvothermal conditions using ionic liquid as a medium and structurally characterized by single-crystal X-ray diffractions. The compound crystallizes in the monoclinic, space group P2(1)/n, a=8.089(8)Å, b=13.977(12)Å, c=8.441(8)Å, β=112.517(11)°, Z=2, V=881.7(14)Å3, R 1=0.03, wR2=0.079 and S=1.01. Its structure consists of a 1-D straight chain that is built of the alternative linkage of mutually perpendicular four-member rings. Other characterizations by IR and thermal and elemental analyses are also described.

AB - A novel borophosphate compound has been synthesized under solvothermal conditions using ionic liquid as a medium and structurally characterized by single-crystal X-ray diffractions. The compound crystallizes in the monoclinic, space group P2(1)/n, a=8.089(8)Å, b=13.977(12)Å, c=8.441(8)Å, β=112.517(11)°, Z=2, V=881.7(14)Å3, R 1=0.03, wR2=0.079 and S=1.01. Its structure consists of a 1-D straight chain that is built of the alternative linkage of mutually perpendicular four-member rings. Other characterizations by IR and thermal and elemental analyses are also described.

KW - Borophosphate

KW - Characterization

KW - Ionic liquid

KW - Medium

KW - Single crystal

KW - Solvothermal technique

KW - Straight chain

KW - Structure

KW - Tetrahedra

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/0242541095

U2 - 10.1016/S0022-4596(03)00340-2

DO - 10.1016/S0022-4596(03)00340-2

M3 - 文章

AN - SCOPUS:0242541095

SN - 0022-4596

VL - 176

SP - 33

EP - 36

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 1

ER -

Impetus for solvothermal synthesis technique: Synthesis and structure of a novel 1-D borophosphate using ionic liquid as medium

Abstract

Keywords

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