Hydrothermal synthesis of MWW-type zirconosilicate

Ailing Lv; Yueming Liu; Xiaohong Li; Haihong Wu; Na Liu; Mingyuan He; Peng Wu

doi:10.1016/S0167-2991(08)80223-6

Hydrothermal synthesis of MWW-type zirconosilicate

Ailing Lv^*, Yueming Liu, Xiaohong Li, Haihong Wu, Na Liu, Mingyuan He, Peng Wu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

1 Scopus citations

Abstract

A novel zirconosilicate with the MWW topology (Zr-MWW) is hydrothermally synthesized for the first time using hexamethyleneimine (HMI) or piperidine (PI) as a structuring direct agent (SDA) and boric acid as a crystallization-supporting agent in an alkali media, which implies new route for preparing MWW-type metallosilicate. Highly crystalline Zr-MWW is crystallized from the gels even with a Si/Zr ratio of 50. Zr-MWW is shown to be efficient for the Lewis acid-catalyzed reduction of cyclic ketones with secondary alcohols_in Meerwein-Ponndorf-Verley (MPV) reactions.

Original language	English
Title of host publication	Zeolites and related materials
Subtitle of host publication	Trends, targets and challenges
Editors	Antoine Gedeon, Pascale Massiani, Florence Babonneau
Pages	385-388
Number of pages	4
Edition	SUPPL. PART A
DOIs	https://doi.org/10.1016/S0167-2991(08)80223-6
State	Published - 2008

Publication series

Name	Studies in Surface Science and Catalysis
Number	SUPPL. PART A
Volume	174
ISSN (Print)	0167-2991

Keywords

Lewis acid
MPV reaction
Zr-MWW
hydrothermal synthesis

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10.1016/S0167-2991(08)80223-6

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Lv, A., Liu, Y., Li, X., Wu, H., Liu, N., He, M., & Wu, P. (2008). Hydrothermal synthesis of MWW-type zirconosilicate. In A. Gedeon, P. Massiani, & F. Babonneau (Eds.), Zeolites and related materials: Trends, targets and challenges (SUPPL. PART A ed., pp. 385-388). (Studies in Surface Science and Catalysis; Vol. 174, No. SUPPL. PART A). https://doi.org/10.1016/S0167-2991(08)80223-6

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title = "Hydrothermal synthesis of MWW-type zirconosilicate",

abstract = "A novel zirconosilicate with the MWW topology (Zr-MWW) is hydrothermally synthesized for the first time using hexamethyleneimine (HMI) or piperidine (PI) as a structuring direct agent (SDA) and boric acid as a crystallization-supporting agent in an alkali media, which implies new route for preparing MWW-type metallosilicate. Highly crystalline Zr-MWW is crystallized from the gels even with a Si/Zr ratio of 50. Zr-MWW is shown to be efficient for the Lewis acid-catalyzed reduction of cyclic ketones with secondary alcohols\_in Meerwein-Ponndorf-Verley (MPV) reactions.",

keywords = "Lewis acid, MPV reaction, Zr-MWW, hydrothermal synthesis",

author = "Ailing Lv and Yueming Liu and Xiaohong Li and Haihong Wu and Na Liu and Mingyuan He and Peng Wu",

year = "2008",

doi = "10.1016/S0167-2991(08)80223-6",

language = "英语",

isbn = "9780444532961",

series = "Studies in Surface Science and Catalysis",

number = "SUPPL. PART A",

pages = "385--388",

editor = "Antoine Gedeon and Pascale Massiani and Florence Babonneau",

booktitle = "Zeolites and related materials",

edition = "SUPPL. PART A",

}

Hydrothermal synthesis of MWW-type zirconosilicate. / Lv, Ailing; Liu, Yueming ; Li, Xiaohong et al.
Zeolites and related materials: Trends, targets and challenges. ed. / Antoine Gedeon; Pascale Massiani; Florence Babonneau. SUPPL. PART A. ed. 2008. p. 385-388 (Studies in Surface Science and Catalysis; Vol. 174, No. SUPPL. PART A).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Hydrothermal synthesis of MWW-type zirconosilicate

AU - Lv, Ailing

AU - Liu, Yueming

AU - Li, Xiaohong

AU - Wu, Haihong

AU - Liu, Na

AU - He, Mingyuan

AU - Wu, Peng

PY - 2008

Y1 - 2008

N2 - A novel zirconosilicate with the MWW topology (Zr-MWW) is hydrothermally synthesized for the first time using hexamethyleneimine (HMI) or piperidine (PI) as a structuring direct agent (SDA) and boric acid as a crystallization-supporting agent in an alkali media, which implies new route for preparing MWW-type metallosilicate. Highly crystalline Zr-MWW is crystallized from the gels even with a Si/Zr ratio of 50. Zr-MWW is shown to be efficient for the Lewis acid-catalyzed reduction of cyclic ketones with secondary alcohols_in Meerwein-Ponndorf-Verley (MPV) reactions.

AB - A novel zirconosilicate with the MWW topology (Zr-MWW) is hydrothermally synthesized for the first time using hexamethyleneimine (HMI) or piperidine (PI) as a structuring direct agent (SDA) and boric acid as a crystallization-supporting agent in an alkali media, which implies new route for preparing MWW-type metallosilicate. Highly crystalline Zr-MWW is crystallized from the gels even with a Si/Zr ratio of 50. Zr-MWW is shown to be efficient for the Lewis acid-catalyzed reduction of cyclic ketones with secondary alcohols_in Meerwein-Ponndorf-Verley (MPV) reactions.

KW - Lewis acid

KW - MPV reaction

KW - Zr-MWW

KW - hydrothermal synthesis

UR - https://www.scopus.com/pages/publications/56249119550

U2 - 10.1016/S0167-2991(08)80223-6

DO - 10.1016/S0167-2991(08)80223-6

M3 - 章节

AN - SCOPUS:56249119550

SN - 9780444532961

T3 - Studies in Surface Science and Catalysis

SP - 385

EP - 388

BT - Zeolites and related materials

A2 - Gedeon, Antoine

A2 - Massiani, Pascale

A2 - Babonneau, Florence

ER -

Hydrothermal synthesis of MWW-type zirconosilicate

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