Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents

Na Liu; Yueming Liu; Wei Xie; Lingling Wang; Mingyuan He; Peng Wu

doi:10.1016/S0167-2991(07)80877-9

Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents

Na Liu^*
, Yueming Liu
, Wei Xie
, Lingling Wang
, Mingyuan He
, Peng Wu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

27 Scopus citations

Abstract

Ti-MWW has been hydrothermally synthesized for the first time in the absence of crystallization-supporting agent of boron acid by means of cooperative templating effects of N,N,N-trimethyl-1-adamantammonium hydroxide (1-TMAda⁺OH^-) and hexamethyleneimine (HMI). The use of potassium cations as a mineralization agent was also necessary for the crystallization. Boron-free Ti-MWW catalysts thus prepared showed a superior activity to boron-containing one in the liquid-phase epoxidation of alkenes with H₂O₂.

Original language	English
Title of host publication	From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
Publisher	Elsevier Inc.
Pages	464-469
Number of pages	6
Edition	A
ISBN (Print)	0444530681, 9780444530684
DOIs	https://doi.org/10.1016/S0167-2991(07)80877-9
State	Published - 2007

Publication series

Name	Studies in Surface Science and Catalysis
Number	A
Volume	170
ISSN (Print)	0167-2991

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10.1016/S0167-2991(07)80877-9

Cite this

Liu, N., Liu, Y., Xie, W., Wang, L., He, M., & Wu, P. (2007). Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference (A ed., pp. 464-469). (Studies in Surface Science and Catalysis; Vol. 170, No. A). Elsevier Inc.. https://doi.org/10.1016/S0167-2991(07)80877-9

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title = "Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents",

abstract = "Ti-MWW has been hydrothermally synthesized for the first time in the absence of crystallization-supporting agent of boron acid by means of cooperative templating effects of N,N,N-trimethyl-1-adamantammonium hydroxide (1-TMAda+OH-) and hexamethyleneimine (HMI). The use of potassium cations as a mineralization agent was also necessary for the crystallization. Boron-free Ti-MWW catalysts thus prepared showed a superior activity to boron-containing one in the liquid-phase epoxidation of alkenes with H2O2.",

author = "Na Liu and Yueming Liu and Wei Xie and Lingling Wang and Mingyuan He and Peng Wu",

year = "2007",

doi = "10.1016/S0167-2991(07)80877-9",

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isbn = "0444530681",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier Inc.",

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Liu, N, Liu, Y, Xie, W, Wang, L, He, M & Wu, P 2007, Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents. in From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. A edn, Studies in Surface Science and Catalysis, no. A, vol. 170, Elsevier Inc., pp. 464-469. https://doi.org/10.1016/S0167-2991(07)80877-9

Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents. / Liu, Na; Liu, Yueming; Xie, Wei et al.
From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. A. ed. Elsevier Inc., 2007. p. 464-469 (Studies in Surface Science and Catalysis; Vol. 170, No. A).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents

AU - Liu, Na

AU - Liu, Yueming

AU - Xie, Wei

AU - Wang, Lingling

AU - He, Mingyuan

AU - Wu, Peng

PY - 2007

Y1 - 2007

N2 - Ti-MWW has been hydrothermally synthesized for the first time in the absence of crystallization-supporting agent of boron acid by means of cooperative templating effects of N,N,N-trimethyl-1-adamantammonium hydroxide (1-TMAda+OH-) and hexamethyleneimine (HMI). The use of potassium cations as a mineralization agent was also necessary for the crystallization. Boron-free Ti-MWW catalysts thus prepared showed a superior activity to boron-containing one in the liquid-phase epoxidation of alkenes with H2O2.

AB - Ti-MWW has been hydrothermally synthesized for the first time in the absence of crystallization-supporting agent of boron acid by means of cooperative templating effects of N,N,N-trimethyl-1-adamantammonium hydroxide (1-TMAda+OH-) and hexamethyleneimine (HMI). The use of potassium cations as a mineralization agent was also necessary for the crystallization. Boron-free Ti-MWW catalysts thus prepared showed a superior activity to boron-containing one in the liquid-phase epoxidation of alkenes with H2O2.

UR - https://www.scopus.com/pages/publications/35348899518

U2 - 10.1016/S0167-2991(07)80877-9

DO - 10.1016/S0167-2991(07)80877-9

M3 - 章节

AN - SCOPUS:35348899518

SN - 0444530681

SN - 9780444530684

T3 - Studies in Surface Science and Catalysis

SP - 464

EP - 469

BT - From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference

PB - Elsevier Inc.

ER -

Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents

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