Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions without Any Additive

Huizhen Liu; Youdi Yang; Hangyu Liu; Shaopeng Li; Chunjun Chen; Tianbin Wu; Qingqing Mei; Yanyan Wang; Bingfeng Chen; Buxing Han

doi:10.1021/acssuschemeng.8b04937

Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions without Any Additive

Huizhen Liu^*
, Youdi Yang
, Hangyu Liu
, Shaopeng Li
, Chunjun Chen
, Tianbin Wu
, Qingqing Mei
, Yanyan Wang
, Bingfeng Chen
, Buxing Han

^*Corresponding author for this work

Peking University
University of Chinese Academy of Sciences
Huairou National Comprehensive Science Center

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

The hydrogenolysis of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) is a very significant reaction, and it is a typical route for producing important chemicals from biomass. Efficient catalysts without any additive for the hydrogenolysis of HMF to DMF under mild conditions are highly desirable. Herein, we found that the Pd/C catalyst prepared in γ-valerolactone (Pd-GVL/C) is an efficient catalyst for the hydrogenolysis of HMF to DMF, and 95.6% of DMF could be obtained at 80 °C without any additive. The GVL interacted with Pd particles and enhanced the activity of the catalyst. It is the first example to achieve the hydrogenolysis of HMF to DMF below 100 °C without any additive.

Original language	English
Pages (from-to)	5711-5716
Number of pages	6
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	6
DOIs	https://doi.org/10.1021/acssuschemeng.8b04937
State	Published - 18 Mar 2019
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

5-Hydroxymethylfurfural
Biomass conversion
Catalysis
Organic modifiers
Selective hydrogenolysis

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10.1021/acssuschemeng.8b04937

Cite this

@article{aaead8267a1f4ae5a9e83d0a86d2fcaf,

title = "Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions without Any Additive",

abstract = "The hydrogenolysis of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) is a very significant reaction, and it is a typical route for producing important chemicals from biomass. Efficient catalysts without any additive for the hydrogenolysis of HMF to DMF under mild conditions are highly desirable. Herein, we found that the Pd/C catalyst prepared in γ-valerolactone (Pd-GVL/C) is an efficient catalyst for the hydrogenolysis of HMF to DMF, and 95.6\% of DMF could be obtained at 80 °C without any additive. The GVL interacted with Pd particles and enhanced the activity of the catalyst. It is the first example to achieve the hydrogenolysis of HMF to DMF below 100 °C without any additive.",

keywords = "5-Hydroxymethylfurfural, Biomass conversion, Catalysis, Organic modifiers, Selective hydrogenolysis",

author = "Huizhen Liu and Youdi Yang and Hangyu Liu and Shaopeng Li and Chunjun Chen and Tianbin Wu and Qingqing Mei and Yanyan Wang and Bingfeng Chen and Buxing Han",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = mar,

day = "18",

doi = "10.1021/acssuschemeng.8b04937",

language = "英语",

volume = "7",

pages = "5711--5716",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions without Any Additive

AU - Liu, Huizhen

AU - Yang, Youdi

AU - Liu, Hangyu

AU - Li, Shaopeng

AU - Chen, Chunjun

AU - Wu, Tianbin

AU - Mei, Qingqing

AU - Wang, Yanyan

AU - Chen, Bingfeng

AU - Han, Buxing

PY - 2019/3/18

Y1 - 2019/3/18

N2 - The hydrogenolysis of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) is a very significant reaction, and it is a typical route for producing important chemicals from biomass. Efficient catalysts without any additive for the hydrogenolysis of HMF to DMF under mild conditions are highly desirable. Herein, we found that the Pd/C catalyst prepared in γ-valerolactone (Pd-GVL/C) is an efficient catalyst for the hydrogenolysis of HMF to DMF, and 95.6% of DMF could be obtained at 80 °C without any additive. The GVL interacted with Pd particles and enhanced the activity of the catalyst. It is the first example to achieve the hydrogenolysis of HMF to DMF below 100 °C without any additive.

AB - The hydrogenolysis of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) is a very significant reaction, and it is a typical route for producing important chemicals from biomass. Efficient catalysts without any additive for the hydrogenolysis of HMF to DMF under mild conditions are highly desirable. Herein, we found that the Pd/C catalyst prepared in γ-valerolactone (Pd-GVL/C) is an efficient catalyst for the hydrogenolysis of HMF to DMF, and 95.6% of DMF could be obtained at 80 °C without any additive. The GVL interacted with Pd particles and enhanced the activity of the catalyst. It is the first example to achieve the hydrogenolysis of HMF to DMF below 100 °C without any additive.

KW - 5-Hydroxymethylfurfural

KW - Biomass conversion

KW - Catalysis

KW - Organic modifiers

KW - Selective hydrogenolysis

UR - https://www.scopus.com/pages/publications/85062832608

U2 - 10.1021/acssuschemeng.8b04937

DO - 10.1021/acssuschemeng.8b04937

M3 - 文章

AN - SCOPUS:85062832608

SN - 2168-0485

VL - 7

SP - 5711

EP - 5716

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 6

ER -

Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions without Any Additive

Abstract

UN SDGs

Keywords

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