Hydrogenation of γ-valerolactone in ethanol over Pd nanoparticles supported on sulfonic acid functionalized MIL-101

Damin Zhang; Feiyang Ye; Yejun Guan; Yimeng Wang; Emiel J.M. Hensen

doi:10.1039/c4ra05250a

Hydrogenation of γ-valerolactone in ethanol over Pd nanoparticles supported on sulfonic acid functionalized MIL-101

Damin Zhang
, Feiyang Ye
, Yejun Guan^*
, Yimeng Wang
, Emiel J.M. Hensen

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Eindhoven University of Technology

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

A ligand-based solid solution approach is employed to incorporate sulphonic acid functional groups into the porous coordination polymer Cr-MIL-101. Loaded with Pd nanoparticles these Pd/MIL-101-SO₃H materials act as bifunctional catalysts for the one-pot conversion of γ-valerolactone into ethyl valerate (up to 83% yield). The catalysts were extensively characterized before and after reaction. The influence of the sulfonic acid group density and the reaction conditions on the catalytic activity was systematically investigated and the reaction network for γ-valerolactone upgrading was discussed.

Original language	English
Pages (from-to)	39558-39564
Number of pages	7
Journal	RSC Advances
Volume	4
Issue number	74
DOIs	https://doi.org/10.1039/c4ra05250a
State	Published - 2014

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title = "Hydrogenation of γ-valerolactone in ethanol over Pd nanoparticles supported on sulfonic acid functionalized MIL-101",

abstract = "A ligand-based solid solution approach is employed to incorporate sulphonic acid functional groups into the porous coordination polymer Cr-MIL-101. Loaded with Pd nanoparticles these Pd/MIL-101-SO3H materials act as bifunctional catalysts for the one-pot conversion of γ-valerolactone into ethyl valerate (up to 83\% yield). The catalysts were extensively characterized before and after reaction. The influence of the sulfonic acid group density and the reaction conditions on the catalytic activity was systematically investigated and the reaction network for γ-valerolactone upgrading was discussed.",

author = "Damin Zhang and Feiyang Ye and Yejun Guan and Yimeng Wang and Hensen, \{Emiel J.M.\}",

year = "2014",

doi = "10.1039/c4ra05250a",

language = "英语",

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pages = "39558--39564",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

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T1 - Hydrogenation of γ-valerolactone in ethanol over Pd nanoparticles supported on sulfonic acid functionalized MIL-101

AU - Zhang, Damin

AU - Ye, Feiyang

AU - Guan, Yejun

AU - Wang, Yimeng

AU - Hensen, Emiel J.M.

PY - 2014

Y1 - 2014

N2 - A ligand-based solid solution approach is employed to incorporate sulphonic acid functional groups into the porous coordination polymer Cr-MIL-101. Loaded with Pd nanoparticles these Pd/MIL-101-SO3H materials act as bifunctional catalysts for the one-pot conversion of γ-valerolactone into ethyl valerate (up to 83% yield). The catalysts were extensively characterized before and after reaction. The influence of the sulfonic acid group density and the reaction conditions on the catalytic activity was systematically investigated and the reaction network for γ-valerolactone upgrading was discussed.

AB - A ligand-based solid solution approach is employed to incorporate sulphonic acid functional groups into the porous coordination polymer Cr-MIL-101. Loaded with Pd nanoparticles these Pd/MIL-101-SO3H materials act as bifunctional catalysts for the one-pot conversion of γ-valerolactone into ethyl valerate (up to 83% yield). The catalysts were extensively characterized before and after reaction. The influence of the sulfonic acid group density and the reaction conditions on the catalytic activity was systematically investigated and the reaction network for γ-valerolactone upgrading was discussed.

UR - https://www.scopus.com/pages/publications/84906871316

U2 - 10.1039/c4ra05250a

DO - 10.1039/c4ra05250a

M3 - 文章

AN - SCOPUS:84906871316

SN - 2046-2069

VL - 4

SP - 39558

EP - 39564

JO - RSC Advances

JF - RSC Advances

IS - 74

ER -

Hydrogenation of γ-valerolactone in ethanol over Pd nanoparticles supported on sulfonic acid functionalized MIL-101

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