Hybrid triazolium and ammonium ions-contained hyperbranched polymer with enhanced ionic conductivity

Hongfei Li; Cuifang Wang; Xiaojuan Liao; Meiran Xie; Ruyi Sun

doi:10.1016/j.polymer.2017.02.023

Hybrid triazolium and ammonium ions-contained hyperbranched polymer with enhanced ionic conductivity

Hongfei Li, Cuifang Wang, Xiaojuan Liao, Meiran Xie, Ruyi Sun

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Hyperbranched poly(triazole) with tertiary amine moiety and longer flexible polyethylene glycol (PEG) terminal group (hb-PTA-PEG) was synthesized by successive Cu(I)-catalyzed azide-alkyne cycloaddition polymerization, and the corresponding hyperbranched poly(triazolium)s containing hybrid quaternary ammonium ion, [hb-PTA-PEG]⁺[I]⁻ and [hb-PTA-PEG]⁺[TFSI]⁻, were obtained after N-alkylation and anion exchange reactions. These hyperbranched polymers presented broad electrochemical stability window of above 6.0 V versus Ag⁺/Ag and 5.3 V versus Li⁺/Li, and displayed low glass transition temperature in the range of −13 to −37 °C, owing to the hyperbranched structure combined with the hybrid ionic moiety and longer flexible PEG end-group. The ionic [hb-PTA-PEG]⁺[TFSI]⁻ showed superior ionic conductivity, which was above 10⁻⁵ S cm⁻¹ at 30 °C.

Original language	English
Pages (from-to)	297-305
Number of pages	9
Journal	Polymer
Volume	112
DOIs	https://doi.org/10.1016/j.polymer.2017.02.023
State	Published - 10 Mar 2017

Keywords

Electrochemical stability
Hyperbranched poly(triazolium)
Ionic conductivity
Quaternary ammonium ion
Thermal properties

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10.1016/j.polymer.2017.02.023

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title = "Hybrid triazolium and ammonium ions-contained hyperbranched polymer with enhanced ionic conductivity",

abstract = "Hyperbranched poly(triazole) with tertiary amine moiety and longer flexible polyethylene glycol (PEG) terminal group (hb-PTA-PEG) was synthesized by successive Cu(I)-catalyzed azide-alkyne cycloaddition polymerization, and the corresponding hyperbranched poly(triazolium)s containing hybrid quaternary ammonium ion, [hb-PTA-PEG]+[I]− and [hb-PTA-PEG]+[TFSI]−, were obtained after N-alkylation and anion exchange reactions. These hyperbranched polymers presented broad electrochemical stability window of above 6.0 V versus Ag+/Ag and 5.3 V versus Li+/Li, and displayed low glass transition temperature in the range of −13 to −37 °C, owing to the hyperbranched structure combined with the hybrid ionic moiety and longer flexible PEG end-group. The ionic [hb-PTA-PEG]+[TFSI]− showed superior ionic conductivity, which was above 10−5 S cm−1 at 30 °C.",

keywords = "Electrochemical stability, Hyperbranched poly(triazolium), Ionic conductivity, Quaternary ammonium ion, Thermal properties",

author = "Hongfei Li and Cuifang Wang and Xiaojuan Liao and Meiran Xie and Ruyi Sun",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

month = mar,

day = "10",

doi = "10.1016/j.polymer.2017.02.023",

language = "英语",

volume = "112",

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TY - JOUR

T1 - Hybrid triazolium and ammonium ions-contained hyperbranched polymer with enhanced ionic conductivity

AU - Li, Hongfei

AU - Wang, Cuifang

AU - Liao, Xiaojuan

AU - Xie, Meiran

AU - Sun, Ruyi

PY - 2017/3/10

Y1 - 2017/3/10

N2 - Hyperbranched poly(triazole) with tertiary amine moiety and longer flexible polyethylene glycol (PEG) terminal group (hb-PTA-PEG) was synthesized by successive Cu(I)-catalyzed azide-alkyne cycloaddition polymerization, and the corresponding hyperbranched poly(triazolium)s containing hybrid quaternary ammonium ion, [hb-PTA-PEG]+[I]− and [hb-PTA-PEG]+[TFSI]−, were obtained after N-alkylation and anion exchange reactions. These hyperbranched polymers presented broad electrochemical stability window of above 6.0 V versus Ag+/Ag and 5.3 V versus Li+/Li, and displayed low glass transition temperature in the range of −13 to −37 °C, owing to the hyperbranched structure combined with the hybrid ionic moiety and longer flexible PEG end-group. The ionic [hb-PTA-PEG]+[TFSI]− showed superior ionic conductivity, which was above 10−5 S cm−1 at 30 °C.

AB - Hyperbranched poly(triazole) with tertiary amine moiety and longer flexible polyethylene glycol (PEG) terminal group (hb-PTA-PEG) was synthesized by successive Cu(I)-catalyzed azide-alkyne cycloaddition polymerization, and the corresponding hyperbranched poly(triazolium)s containing hybrid quaternary ammonium ion, [hb-PTA-PEG]+[I]− and [hb-PTA-PEG]+[TFSI]−, were obtained after N-alkylation and anion exchange reactions. These hyperbranched polymers presented broad electrochemical stability window of above 6.0 V versus Ag+/Ag and 5.3 V versus Li+/Li, and displayed low glass transition temperature in the range of −13 to −37 °C, owing to the hyperbranched structure combined with the hybrid ionic moiety and longer flexible PEG end-group. The ionic [hb-PTA-PEG]+[TFSI]− showed superior ionic conductivity, which was above 10−5 S cm−1 at 30 °C.

KW - Electrochemical stability

KW - Hyperbranched poly(triazolium)

KW - Ionic conductivity

KW - Quaternary ammonium ion

KW - Thermal properties

UR - https://www.scopus.com/pages/publications/85012050873

U2 - 10.1016/j.polymer.2017.02.023

DO - 10.1016/j.polymer.2017.02.023

M3 - 文章

AN - SCOPUS:85012050873

SN - 0032-3861

VL - 112

SP - 297

EP - 305

JO - Polymer

JF - Polymer

ER -

Hybrid triazolium and ammonium ions-contained hyperbranched polymer with enhanced ionic conductivity

Abstract

Keywords

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