Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides

Xin Zhang Yu; Wen Long Wei; Yu Lan Niu; Xing Li; Ming Wang; Wen Chao Gao

doi:10.3390/molecules27196232

Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides

Xin Zhang Yu
, Wen Long Wei
, Yu Lan Niu^*
, Xing Li
, Ming Wang
, Wen Chao Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Taiyuan Institute of Technology
Taiyuan University of Technology
East China Normal University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)₂ catalysis, whereas symmetrical diaryl sulfides were exclusively yielded in the presence of the reductive Fe/HCl system.

Original language	English
Article number	6232
Journal	Molecules
Volume	27
Issue number	19
DOIs	https://doi.org/10.3390/molecules27196232
State	Published - Oct 2022

Keywords

diaryl disulfides
diaryl sulfides
homocoupling
sodium arenesulfinates
symmetric

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10.3390/molecules27196232

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title = "Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides",

abstract = "Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)2 catalysis, whereas symmetrical diaryl sulfides were exclusively yielded in the presence of the reductive Fe/HCl system.",

keywords = "diaryl disulfides, diaryl sulfides, homocoupling, sodium arenesulfinates, symmetric",

author = "Yu, \{Xin Zhang\} and Wei, \{Wen Long\} and Niu, \{Yu Lan\} and Xing Li and Ming Wang and Gao, \{Wen Chao\}",

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doi = "10.3390/molecules27196232",

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T1 - Homocouplings of Sodium Arenesulfinates

T2 - Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides

AU - Yu, Xin Zhang

AU - Wei, Wen Long

AU - Niu, Yu Lan

AU - Li, Xing

AU - Wang, Ming

AU - Gao, Wen Chao

PY - 2022/10

Y1 - 2022/10

N2 - Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)2 catalysis, whereas symmetrical diaryl sulfides were exclusively yielded in the presence of the reductive Fe/HCl system.

AB - Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)2 catalysis, whereas symmetrical diaryl sulfides were exclusively yielded in the presence of the reductive Fe/HCl system.

KW - diaryl disulfides

KW - diaryl sulfides

KW - homocoupling

KW - sodium arenesulfinates

KW - symmetric

UR - https://www.scopus.com/pages/publications/85139941663

U2 - 10.3390/molecules27196232

DO - 10.3390/molecules27196232

M3 - 文章

C2 - 36234770

AN - SCOPUS:85139941663

SN - 1420-3049

VL - 27

JO - Molecules

JF - Molecules

IS - 19

M1 - 6232

ER -

Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides

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Keywords

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