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Homocoupling of aryl iodides catalyzed by cyclopalladated complexes of tertiary arylamines

  • Qiang Li
  • , Juan Nie
  • , Fan Yang
  • , Rui Zheng
  • , Gang Zou
  • , Jie Tang*
  • *Corresponding author for this work
  • East China Normal University

Research output: Contribution to journalArticlepeer-review

Abstract

Homocoupling of aryl iodides catalyzed by cyclopalladated complexes of tertiary arylamines gives symmetric biaryls with good yields in DMA or ionic liquid [Bmim]BF4. This catalytic alternative of the Ullmann reaction has proved to be sensitive to both electronic and steric factors of substrates.

Original languageEnglish
Pages (from-to)419-421
Number of pages3
JournalChinese Journal of Chemistry
Volume22
Issue number5
DOIs
StatePublished - May 2004

Keywords

  • Aryl iodide
  • Cyclopalladated complex
  • Homocoupling
  • Ionic liquid
  • Tertiary arylamine

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