Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C2-symmetric spiroketal bisphosphine/Au(I) complex

Zhong Yan Cao; Xiaoming Wang; Chen Tan; Xiao Li Zhao; Jian Zhou; Kuiling Ding

doi:10.1021/ja4040895

Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C₂-symmetric spiroketal bisphosphine/Au(I) complex

Zhong Yan Cao
, Xiaoming Wang
, Chen Tan
, Xiao Li Zhao
, Jian Zhou^*
, Kuiling Ding

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
CAS - Shanghai Institute of Organic Chemistry

Research output: Contribution to journal › Article › peer-review

344 Scopus citations

Abstract

A spiroketal bisphosphine (SKP) derived chiral digold complex is identified as a powerful catalyst for the highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles from diazooxindoles and a broad range of alkenes, including both cis and trans 1,2-disubstituted alkenes.

Original language	English
Pages (from-to)	8197-8200
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	22
DOIs	https://doi.org/10.1021/ja4040895
State	Published - 5 Jun 2013

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10.1021/ja4040895

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title = "Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C2-symmetric spiroketal bisphosphine/Au(I) complex",

abstract = "A spiroketal bisphosphine (SKP) derived chiral digold complex is identified as a powerful catalyst for the highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles from diazooxindoles and a broad range of alkenes, including both cis and trans 1,2-disubstituted alkenes.",

author = "Cao, \{Zhong Yan\} and Xiaoming Wang and Chen Tan and Zhao, \{Xiao Li\} and Jian Zhou and Kuiling Ding",

year = "2013",

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doi = "10.1021/ja4040895",

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volume = "135",

pages = "8197--8200",

journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C2-symmetric spiroketal bisphosphine/Au(I) complex

AU - Cao, Zhong Yan

AU - Wang, Xiaoming

AU - Tan, Chen

AU - Zhao, Xiao Li

AU - Zhou, Jian

AU - Ding, Kuiling

PY - 2013/6/5

Y1 - 2013/6/5

N2 - A spiroketal bisphosphine (SKP) derived chiral digold complex is identified as a powerful catalyst for the highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles from diazooxindoles and a broad range of alkenes, including both cis and trans 1,2-disubstituted alkenes.

AB - A spiroketal bisphosphine (SKP) derived chiral digold complex is identified as a powerful catalyst for the highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles from diazooxindoles and a broad range of alkenes, including both cis and trans 1,2-disubstituted alkenes.

UR - https://www.scopus.com/pages/publications/84878651009

U2 - 10.1021/ja4040895

DO - 10.1021/ja4040895

M3 - 文章

AN - SCOPUS:84878651009

SN - 0002-7863

VL - 135

SP - 8197

EP - 8200

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 22

ER -

Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C₂-symmetric spiroketal bisphosphine/Au(I) complex

Abstract

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