Highly Stereoselective Direct Construction of Diaryl-Substituted Cyclobutanes†

Xiang Yang Song; Liu Peng Zhao; Lijia Wang; Yong Tang

doi:10.1002/cjoc.201900456

Highly Stereoselective Direct Construction of Diaryl-Substituted Cyclobutanes^†

Xiang Yang Song, Liu Peng Zhao, Lijia Wang, Yong Tang

School of Chemistry and Molecular Engineering

CAS - Shanghai Institute of Organic Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A copper catalyzed stereoselective [2+2] cyclization has been developed, providing a concise protocol to the direct construction of diaryl-substituted cyclobutanes in up to 99% yield with up to >95/5 dr. Meanwhile, the enantioselective version of this reaction has also been achieved, leading to a series of optically active diaryl-substituted cyclobutanes with up to 94% ee.

Original language	English
Pages (from-to)	259-262
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	38
Issue number	3
DOIs	https://doi.org/10.1002/cjoc.201900456
State	Published - 1 Mar 2020

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title = "Highly Stereoselective Direct Construction of Diaryl-Substituted Cyclobutanes† ",

abstract = "A copper catalyzed stereoselective [2+2] cyclization has been developed, providing a concise protocol to the direct construction of diaryl-substituted cyclobutanes in up to 99\% yield with up to >95/5 dr. Meanwhile, the enantioselective version of this reaction has also been achieved, leading to a series of optically active diaryl-substituted cyclobutanes with up to 94\% ee.",

author = "Song, \{Xiang Yang\} and Zhao, \{Liu Peng\} and Lijia Wang and Yong Tang",

note = "Publisher Copyright: {\textcopyright} 2020 SIOC, CAS, Shanghai, \& WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

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AU - Song, Xiang Yang

AU - Zhao, Liu Peng

AU - Wang, Lijia

AU - Tang, Yong

PY - 2020/3/1

Y1 - 2020/3/1

N2 - A copper catalyzed stereoselective [2+2] cyclization has been developed, providing a concise protocol to the direct construction of diaryl-substituted cyclobutanes in up to 99% yield with up to >95/5 dr. Meanwhile, the enantioselective version of this reaction has also been achieved, leading to a series of optically active diaryl-substituted cyclobutanes with up to 94% ee.

AB - A copper catalyzed stereoselective [2+2] cyclization has been developed, providing a concise protocol to the direct construction of diaryl-substituted cyclobutanes in up to 99% yield with up to >95/5 dr. Meanwhile, the enantioselective version of this reaction has also been achieved, leading to a series of optically active diaryl-substituted cyclobutanes with up to 94% ee.

UR - https://www.scopus.com/pages/publications/85078050317

U2 - 10.1002/cjoc.201900456

DO - 10.1002/cjoc.201900456

M3 - 文章

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SN - 1001-604X

VL - 38

SP - 259

EP - 262

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 3

ER -

Highly Stereoselective Direct Construction of Diaryl-Substituted Cyclobutanes^†

Abstract

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