Abstract
A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yields.
| Original language | English |
|---|---|
| Pages (from-to) | 781-785 |
| Number of pages | 5 |
| Journal | Beilstein Journal of Organic Chemistry |
| Volume | 7 |
| DOIs | |
| State | Published - 8 Jun 2011 |
| Externally published | Yes |
Keywords
- Allylic trichloroacetamides
- Allylic trichloroacetimidate
- Gold(I) chloride
- Overman rearrangement
- Water