Highly chemoselective rearrangement of 3-aryloxaziridines to nitrones or amides

Dong Xing; Xinfang Xu; Liping Yang

doi:10.1055/s-0029-1216965

Highly chemoselective rearrangement of 3-aryloxaziridines to nitrones or amides

Dong Xing
, Xinfang Xu
, Liping Yang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

An efficient method for the chemoselective ring-opening rearrangement of 3-aryloxaziridines by using silver triflate alone to afford nitrones, or in the presence of a simple Br0nsted acid to yield amides, has been developed. Silver triflate plays an important role in both transformations.

Original language	English
Pages (from-to)	3399-3404
Number of pages	6
Journal	Synthesis (Germany)
Issue number	20
DOIs	https://doi.org/10.1055/s-0029-1216965
State	Published - 2009

Keywords

Amides
Chemoselectivity
Nitrones
Oxaziridines
Rearrangement

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10.1055/s-0029-1216965

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title = "Highly chemoselective rearrangement of 3-aryloxaziridines to nitrones or amides",

abstract = "An efficient method for the chemoselective ring-opening rearrangement of 3-aryloxaziridines by using silver triflate alone to afford nitrones, or in the presence of a simple Br0nsted acid to yield amides, has been developed. Silver triflate plays an important role in both transformations.",

keywords = "Amides, Chemoselectivity, Nitrones, Oxaziridines, Rearrangement",

author = "Dong Xing and Xinfang Xu and Liping Yang",

year = "2009",

doi = "10.1055/s-0029-1216965",

language = "英语",

pages = "3399--3404",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "20",

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TY - JOUR

T1 - Highly chemoselective rearrangement of 3-aryloxaziridines to nitrones or amides

AU - Xing, Dong

AU - Xu, Xinfang

AU - Yang, Liping

PY - 2009

Y1 - 2009

N2 - An efficient method for the chemoselective ring-opening rearrangement of 3-aryloxaziridines by using silver triflate alone to afford nitrones, or in the presence of a simple Br0nsted acid to yield amides, has been developed. Silver triflate plays an important role in both transformations.

AB - An efficient method for the chemoselective ring-opening rearrangement of 3-aryloxaziridines by using silver triflate alone to afford nitrones, or in the presence of a simple Br0nsted acid to yield amides, has been developed. Silver triflate plays an important role in both transformations.

KW - Amides

KW - Chemoselectivity

KW - Nitrones

KW - Oxaziridines

KW - Rearrangement

UR - https://www.scopus.com/pages/publications/72049125871

U2 - 10.1055/s-0029-1216965

DO - 10.1055/s-0029-1216965

M3 - 文章

AN - SCOPUS:72049125871

SN - 0039-7881

SP - 3399

EP - 3404

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 20

ER -

Highly chemoselective rearrangement of 3-aryloxaziridines to nitrones or amides

Abstract

Keywords

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