High resolution spectroscopy of B0u+←X0g+ transitions in 130Te2: Reference lines spanning the 443.2–451.4 nm region

  • Qinning Lin
  • , Jie Ma
  • , James Coker
  • , Renjun Pang
  • , Zesen Wang
  • , J. E. Furneaux*
  • , Jianping Yin
  • , Tao Yang
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Molecular tellurium (130Te2) has long been regarded as a promising candidate for a variety of spectroscopic applications, especially as a frequency reference. Absorption lines of 130Te2 were published extensively in the past few decades, however, the spectral resolution was not sufficiently high to be considered a precision spectroscopic reference. Here, a high resolution spectral atlas of 130Te2 Doppler-free saturated absorption transitions is reported, and used to assign multiple ro-vibrational bands in the B(Σu-3)0u+←X(Σu-3)0g+ electronic transition via the Dunham model, giving updated Dunham parameters and diatomic constants for the B(Σu-3)0u+ state at an unprecedented level of precision. Our findings reveal spectroscopic properties of 130Te2 that might eventually contribute to frequency reference in precision measurement such as the quest for non-zero electron's Electric Dipole Moment (eEDM).

Original languageEnglish
Article number123887
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume311
DOIs
StatePublished - 15 Apr 2024
Externally publishedYes

Keywords

  • Diatomic molecules
  • Frequency reference
  • Saturated absorption spectroscopy
  • Tellurium spectrum

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