Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

Ying Zhang; Qi Feng Zhou; Gui Fei Huo; Guang Qiang Yin; Xiao Li Zhao; Bo Jiang; Hongwei Tan; Xiaopeng Li; Hai Bo Yang

doi:10.1021/acs.inorgchem.7b02777

Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

Ying Zhang, Qi Feng Zhou, Gui Fei Huo, Guang Qiang Yin, Xiao Li Zhao, Bo Jiang, Hongwei Tan, Xiaopeng Li, Hai Bo Yang

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Review article › peer-review

41 Scopus citations

Abstract

A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.

Original language	English
Pages (from-to)	3516-3520
Number of pages	5
Journal	Inorganic Chemistry
Volume	57
Issue number	7
DOIs	https://doi.org/10.1021/acs.inorgchem.7b02777
State	Published - 2 Apr 2018

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title = "Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions",

abstract = "A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.",

author = "Ying Zhang and Zhou, \{Qi Feng\} and Huo, \{Gui Fei\} and Yin, \{Guang Qiang\} and Zhao, \{Xiao Li\} and Bo Jiang and Hongwei Tan and Xiaopeng Li and Yang, \{Hai Bo\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2018",

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day = "2",

doi = "10.1021/acs.inorgchem.7b02777",

language = "英语",

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T1 - Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

AU - Zhang, Ying

AU - Zhou, Qi Feng

AU - Huo, Gui Fei

AU - Yin, Guang Qiang

AU - Zhao, Xiao Li

AU - Jiang, Bo

AU - Tan, Hongwei

AU - Li, Xiaopeng

AU - Yang, Hai Bo

PY - 2018/4/2

Y1 - 2018/4/2

N2 - A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.

AB - A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.

UR - https://www.scopus.com/pages/publications/85044727130

U2 - 10.1021/acs.inorgchem.7b02777

DO - 10.1021/acs.inorgchem.7b02777

M3 - 文献综述

C2 - 29251490

AN - SCOPUS:85044727130

SN - 0020-1669

VL - 57

SP - 3516

EP - 3520

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

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