Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

Ying Zhang; Qi Feng Zhou; Gui Fei Huo; Guang Qiang Yin; Xiao Li Zhao; Bo Jiang; Hongwei Tan; Xiaopeng Li; Hai Bo Yang

doi:10.1021/acs.inorgchem.7b02777

Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

Ying Zhang
, Qi Feng Zhou
, Gui Fei Huo
, Guang Qiang Yin
, Xiao Li Zhao
, Bo Jiang^*
, Hongwei Tan
, Xiaopeng Li
, Hai Bo Yang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Beijing Normal University
East China Normal University
University of South Florida

Research output: Contribution to journal › Review article › peer-review

42 Scopus citations

Abstract

A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.

Original language	English
Pages (from-to)	3516-3520
Number of pages	5
Journal	Inorganic Chemistry
Volume	57
Issue number	7
DOIs	https://doi.org/10.1021/acs.inorgchem.7b02777
State	Published - 2 Apr 2018

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title = "Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions",

abstract = "A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.",

author = "Ying Zhang and Zhou, \{Qi Feng\} and Huo, \{Gui Fei\} and Yin, \{Guang Qiang\} and Zhao, \{Xiao Li\} and Bo Jiang and Hongwei Tan and Xiaopeng Li and Yang, \{Hai Bo\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2018",

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day = "2",

doi = "10.1021/acs.inorgchem.7b02777",

language = "英语",

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T1 - Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

AU - Zhang, Ying

AU - Zhou, Qi Feng

AU - Huo, Gui Fei

AU - Yin, Guang Qiang

AU - Zhao, Xiao Li

AU - Jiang, Bo

AU - Tan, Hongwei

AU - Li, Xiaopeng

AU - Yang, Hai Bo

PY - 2018/4/2

Y1 - 2018/4/2

N2 - A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.

AB - A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-Assembly. A study on the hierarchical self-Assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π-π interactions. More interestingly, the metallacage has been found to spontaneously self-Assemble into a transparent metallogel at room temperature without a heating-cooling process.

UR - https://www.scopus.com/pages/publications/85044727130

U2 - 10.1021/acs.inorgchem.7b02777

DO - 10.1021/acs.inorgchem.7b02777

M3 - 文献综述

C2 - 29251490

AN - SCOPUS:85044727130

SN - 0020-1669

VL - 57

SP - 3516

EP - 3520

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Hierarchical self-Assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via pt···Pt and π-π Interactions

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