Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method

H. Zhang; Z. Q. Li; Y. R. Chen; J. J. Li; Z. Sun; Z. Yang; S. M. Huang

doi:10.1142/S0218625X12500345

Growth of Cu ₂ZnSn(S,Se) ₄ thin films by a simple eco-friendly solution route method

H. Zhang
, Z. Q. Li
, Y. R. Chen
, J. J. Li
, Z. Sun
, Z. Yang
, S. M. Huang^*

^*Corresponding author for this work

School of Physics and Electronic Science

East China Normal University
Shanghai Jiao Tong University

Research output: Contribution to journal › Review article › peer-review

5 Scopus citations

Abstract

A simple and hydrazine-free solution-based approach for depositing Cu ₂ZnSnS ₄ (CZTS) and Cu ₂ZnSn(S,Se) ₄ (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH ₃COO) ₂, Zn(CH ₃COO) ₂, SnCl ₂) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44% under AM 1.5 illumination.

Original language	English
Article number	1250034
Journal	Surface Review and Letters
Volume	19
Issue number	4
DOIs	https://doi.org/10.1142/S0218625X12500345
State	Published - Aug 2012

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy
SDG 13 Climate Action

Keywords

Cu ZnSn(S,Se)
selenization
solution
sulfurization
thin film solar cells

Access to Document

10.1142/S0218625X12500345

Cite this

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title = "Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method",

abstract = "A simple and hydrazine-free solution-based approach for depositing Cu 2ZnSnS 4 (CZTS) and Cu 2ZnSn(S,Se) 4 (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH 3COO) 2, Zn(CH 3COO) 2, SnCl 2) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44\% under AM 1.5 illumination.",

keywords = "Cu ZnSn(S,Se), selenization, solution, sulfurization, thin film solar cells",

author = "H. Zhang and Li, \{Z. Q.\} and Chen, \{Y. R.\} and Li, \{J. J.\} and Z. Sun and Z. Yang and Huang, \{S. M.\}",

year = "2012",

month = aug,

doi = "10.1142/S0218625X12500345",

language = "英语",

volume = "19",

journal = "Surface Review and Letters",

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T1 - Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method

AU - Zhang, H.

AU - Li, Z. Q.

AU - Chen, Y. R.

AU - Li, J. J.

AU - Sun, Z.

AU - Yang, Z.

AU - Huang, S. M.

PY - 2012/8

Y1 - 2012/8

N2 - A simple and hydrazine-free solution-based approach for depositing Cu 2ZnSnS 4 (CZTS) and Cu 2ZnSn(S,Se) 4 (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH 3COO) 2, Zn(CH 3COO) 2, SnCl 2) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44% under AM 1.5 illumination.

AB - A simple and hydrazine-free solution-based approach for depositing Cu 2ZnSnS 4 (CZTS) and Cu 2ZnSn(S,Se) 4 (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH 3COO) 2, Zn(CH 3COO) 2, SnCl 2) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44% under AM 1.5 illumination.

KW - Cu ZnSn(S,Se)

KW - selenization

KW - solution

KW - sulfurization

KW - thin film solar cells

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DO - 10.1142/S0218625X12500345

M3 - 文献综述

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JO - Surface Review and Letters

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