Graphene oxide as support for the immobilization of phosphotungstic acid: Application in the selective oxidation of benzyl alcohol

Kun Liu; Tingting Chen; Zhiqiang Hou; Yuanyuan Wang; Liyi Dai

doi:10.1007/s10562-013-1121-4

Graphene oxide as support for the immobilization of phosphotungstic acid: Application in the selective oxidation of benzyl alcohol

Kun Liu
, Tingting Chen
, Zhiqiang Hou
, Yuanyuan Wang
, Liyi Dai^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Graphene oxide functionalized with gamaaminopropyltriethoxysilane, is used as support for the immobilization of homogeneous heteropoly phosphotungstic acid. It is synthesized and characterized by SEM, XPS, XRD, ³¹P NMR and Raman. The effects of catalyst parameters and reaction conditions on the oxidation reaction of benzyl alcohol are systematically investigated. Under optimal conditions, the catalyst exhibit remarkably enhanced catalytic activity (conversion 76 % and selectivity 99 %). And the catalyst could be separated conveniently. Moreover, the loss of PW₁₂O₄₀^3- anion from the support under the reaction conditions is responsible for the deactivation of the catalyst.

Original language	English
Pages (from-to)	314-319
Number of pages	6
Journal	Catalysis Letters
Volume	144
Issue number	2
DOIs	https://doi.org/10.1007/s10562-013-1121-4
State	Published - Feb 2014

Keywords

Benzyl alcohol oxidation
Graphene oxide
Phosphotungstic acid

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10.1007/s10562-013-1121-4

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title = "Graphene oxide as support for the immobilization of phosphotungstic acid: Application in the selective oxidation of benzyl alcohol",

abstract = "Graphene oxide functionalized with gamaaminopropyltriethoxysilane, is used as support for the immobilization of homogeneous heteropoly phosphotungstic acid. It is synthesized and characterized by SEM, XPS, XRD, 31P NMR and Raman. The effects of catalyst parameters and reaction conditions on the oxidation reaction of benzyl alcohol are systematically investigated. Under optimal conditions, the catalyst exhibit remarkably enhanced catalytic activity (conversion 76 \% and selectivity 99 \%). And the catalyst could be separated conveniently. Moreover, the loss of PW12O403- anion from the support under the reaction conditions is responsible for the deactivation of the catalyst.",

keywords = "Benzyl alcohol oxidation, Graphene oxide, Phosphotungstic acid",

author = "Kun Liu and Tingting Chen and Zhiqiang Hou and Yuanyuan Wang and Liyi Dai",

year = "2014",

month = feb,

doi = "10.1007/s10562-013-1121-4",

language = "英语",

volume = "144",

pages = "314--319",

journal = "Catalysis Letters",

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TY - JOUR

T1 - Graphene oxide as support for the immobilization of phosphotungstic acid

T2 - Application in the selective oxidation of benzyl alcohol

AU - Liu, Kun

AU - Chen, Tingting

AU - Hou, Zhiqiang

AU - Wang, Yuanyuan

AU - Dai, Liyi

PY - 2014/2

Y1 - 2014/2

N2 - Graphene oxide functionalized with gamaaminopropyltriethoxysilane, is used as support for the immobilization of homogeneous heteropoly phosphotungstic acid. It is synthesized and characterized by SEM, XPS, XRD, 31P NMR and Raman. The effects of catalyst parameters and reaction conditions on the oxidation reaction of benzyl alcohol are systematically investigated. Under optimal conditions, the catalyst exhibit remarkably enhanced catalytic activity (conversion 76 % and selectivity 99 %). And the catalyst could be separated conveniently. Moreover, the loss of PW12O403- anion from the support under the reaction conditions is responsible for the deactivation of the catalyst.

AB - Graphene oxide functionalized with gamaaminopropyltriethoxysilane, is used as support for the immobilization of homogeneous heteropoly phosphotungstic acid. It is synthesized and characterized by SEM, XPS, XRD, 31P NMR and Raman. The effects of catalyst parameters and reaction conditions on the oxidation reaction of benzyl alcohol are systematically investigated. Under optimal conditions, the catalyst exhibit remarkably enhanced catalytic activity (conversion 76 % and selectivity 99 %). And the catalyst could be separated conveniently. Moreover, the loss of PW12O403- anion from the support under the reaction conditions is responsible for the deactivation of the catalyst.

KW - Benzyl alcohol oxidation

KW - Graphene oxide

KW - Phosphotungstic acid

UR - https://www.scopus.com/pages/publications/84899474207

U2 - 10.1007/s10562-013-1121-4

DO - 10.1007/s10562-013-1121-4

M3 - 文章

AN - SCOPUS:84899474207

SN - 1011-372X

VL - 144

SP - 314

EP - 319

JO - Catalysis Letters

JF - Catalysis Letters

IS - 2

ER -

Graphene oxide as support for the immobilization of phosphotungstic acid: Application in the selective oxidation of benzyl alcohol

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Keywords

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