Graphene nanosheets modified glassy carbon electrode as a highly sensitive and selective voltammetric sensor for rutin

Haijun Du; Jianshan Ye; Jiaqi Zhang; Xiaodan Huang; Chengzhong Yu

doi:10.1002/elan.201000110

Graphene nanosheets modified glassy carbon electrode as a highly sensitive and selective voltammetric sensor for rutin

Haijun Du, Jianshan Ye, Jiaqi Zhang, Xiaodan Huang, Chengzhong Yu

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Graphene nanosheets modified glassy carbon electrode (GNs/GCE) was fabricated as voltammetric sensor for rutin with good sensitivity, selectivity and reproducibility. The sensor exhibits an adsorption-controlled, reversible twoproton and two electron transfer reaction for the oxidation of rutin with a peak-to-peak separation (ΔE_p) of 26 mV as revealed by cyclic voltammetry. Moreover, the redox peak current increased about 14 times than that on bare glassy carbon electrode (GCE). The linear response of the sensor is from 1×10^-7 to 1×10^-5 M with a detection limit of 2.1 × 10^-8 M (S/N = 3). The method was successfully applied to determine rutin in tablets with satisfied recovery.

Original language	English
Pages (from-to)	2399-2406
Number of pages	8
Journal	Electroanalysis
Volume	22
Issue number	20
DOIs	https://doi.org/10.1002/elan.201000110
State	Published - Oct 2010
Externally published	Yes

Keywords

Electrocatalysis
Graphene nanosheets
Rutin
Sensors
Stripping differential pulse voltammetry

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10.1002/elan.201000110

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title = "Graphene nanosheets modified glassy carbon electrode as a highly sensitive and selective voltammetric sensor for rutin",

abstract = "Graphene nanosheets modified glassy carbon electrode (GNs/GCE) was fabricated as voltammetric sensor for rutin with good sensitivity, selectivity and reproducibility. The sensor exhibits an adsorption-controlled, reversible twoproton and two electron transfer reaction for the oxidation of rutin with a peak-to-peak separation (ΔEp) of 26 mV as revealed by cyclic voltammetry. Moreover, the redox peak current increased about 14 times than that on bare glassy carbon electrode (GCE). The linear response of the sensor is from 1×10-7 to 1×10-5 M with a detection limit of 2.1 × 10-8 M (S/N = 3). The method was successfully applied to determine rutin in tablets with satisfied recovery.",

keywords = "Electrocatalysis, Graphene nanosheets, Rutin, Sensors, Stripping differential pulse voltammetry",

author = "Haijun Du and Jianshan Ye and Jiaqi Zhang and Xiaodan Huang and Chengzhong Yu",

year = "2010",

month = oct,

doi = "10.1002/elan.201000110",

language = "英语",

volume = "22",

pages = "2399--2406",

journal = "Electroanalysis",

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TY - JOUR

T1 - Graphene nanosheets modified glassy carbon electrode as a highly sensitive and selective voltammetric sensor for rutin

AU - Du, Haijun

AU - Ye, Jianshan

AU - Zhang, Jiaqi

AU - Huang, Xiaodan

AU - Yu, Chengzhong

PY - 2010/10

Y1 - 2010/10

N2 - Graphene nanosheets modified glassy carbon electrode (GNs/GCE) was fabricated as voltammetric sensor for rutin with good sensitivity, selectivity and reproducibility. The sensor exhibits an adsorption-controlled, reversible twoproton and two electron transfer reaction for the oxidation of rutin with a peak-to-peak separation (ΔEp) of 26 mV as revealed by cyclic voltammetry. Moreover, the redox peak current increased about 14 times than that on bare glassy carbon electrode (GCE). The linear response of the sensor is from 1×10-7 to 1×10-5 M with a detection limit of 2.1 × 10-8 M (S/N = 3). The method was successfully applied to determine rutin in tablets with satisfied recovery.

AB - Graphene nanosheets modified glassy carbon electrode (GNs/GCE) was fabricated as voltammetric sensor for rutin with good sensitivity, selectivity and reproducibility. The sensor exhibits an adsorption-controlled, reversible twoproton and two electron transfer reaction for the oxidation of rutin with a peak-to-peak separation (ΔEp) of 26 mV as revealed by cyclic voltammetry. Moreover, the redox peak current increased about 14 times than that on bare glassy carbon electrode (GCE). The linear response of the sensor is from 1×10-7 to 1×10-5 M with a detection limit of 2.1 × 10-8 M (S/N = 3). The method was successfully applied to determine rutin in tablets with satisfied recovery.

KW - Electrocatalysis

KW - Graphene nanosheets

KW - Rutin

KW - Sensors

KW - Stripping differential pulse voltammetry

UR - https://www.scopus.com/pages/publications/78650263180

U2 - 10.1002/elan.201000110

DO - 10.1002/elan.201000110

M3 - 文章

AN - SCOPUS:78650263180

SN - 1040-0397

VL - 22

SP - 2399

EP - 2406

JO - Electroanalysis

JF - Electroanalysis

IS - 20

ER -

Graphene nanosheets modified glassy carbon electrode as a highly sensitive and selective voltammetric sensor for rutin

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