Gold(I)-Catalyzed Enantioselective Cyclopropanation of α-Aryl Diazoacetates with Enamides

Zhaowei Chu; Zhiqiong Tang; Kenan Zhang; Lei Wang; Wenbo Li; Hai Hong Wu; Junliang Zhang

doi:10.1021/acs.organomet.9b00415

Gold(I)-Catalyzed Enantioselective Cyclopropanation of α-Aryl Diazoacetates with Enamides

Zhaowei Chu
, Zhiqiong Tang
, Kenan Zhang
, Lei Wang
, Wenbo Li^*
, Hai Hong Wu
, Junliang Zhang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A gold-catalyzed enantioselective cyclopropanation of enamides with α-diazoarylacetate compounds was developed, which provides a facile access to synthetically useful densely substituted cyclopropanes in good yields with excellent enantioselectivities and diastereoselectivities.

Original language	English
Pages (from-to)	4036-4042
Number of pages	7
Journal	Organometallics
DOIs	https://doi.org/10.1021/acs.organomet.9b00415
State	Published - 2019

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@article{ac4ceee5f83441718d5201a991881741,

title = "Gold(I)-Catalyzed Enantioselective Cyclopropanation of α-Aryl Diazoacetates with Enamides",

abstract = "A gold-catalyzed enantioselective cyclopropanation of enamides with α-diazoarylacetate compounds was developed, which provides a facile access to synthetically useful densely substituted cyclopropanes in good yields with excellent enantioselectivities and diastereoselectivities.",

author = "Zhaowei Chu and Zhiqiong Tang and Kenan Zhang and Lei Wang and Wenbo Li and Wu, \{Hai Hong\} and Junliang Zhang",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

doi = "10.1021/acs.organomet.9b00415",

language = "英语",

pages = "4036--4042",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

}

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T1 - Gold(I)-Catalyzed Enantioselective Cyclopropanation of α-Aryl Diazoacetates with Enamides

AU - Chu, Zhaowei

AU - Tang, Zhiqiong

AU - Zhang, Kenan

AU - Wang, Lei

AU - Li, Wenbo

AU - Wu, Hai Hong

AU - Zhang, Junliang

PY - 2019

Y1 - 2019

N2 - A gold-catalyzed enantioselective cyclopropanation of enamides with α-diazoarylacetate compounds was developed, which provides a facile access to synthetically useful densely substituted cyclopropanes in good yields with excellent enantioselectivities and diastereoselectivities.

AB - A gold-catalyzed enantioselective cyclopropanation of enamides with α-diazoarylacetate compounds was developed, which provides a facile access to synthetically useful densely substituted cyclopropanes in good yields with excellent enantioselectivities and diastereoselectivities.

UR - https://www.scopus.com/pages/publications/85072642364

U2 - 10.1021/acs.organomet.9b00415

DO - 10.1021/acs.organomet.9b00415

M3 - 文章

AN - SCOPUS:85072642364

SN - 0276-7333

SP - 4036

EP - 4042

JO - Organometallics

JF - Organometallics

ER -

Gold(I)-Catalyzed Enantioselective Cyclopropanation of α-Aryl Diazoacetates with Enamides

Abstract

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