Gold-catalyzed: Para -selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds

Ben Ma; Jiaojiao Wu; Lu Liu; Junliang Zhang

doi:10.1039/c7cc05649d

Gold-catalyzed: Para -selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds

Ben Ma, Jiaojiao Wu, Lu Liu, Junliang Zhang

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Herein, we report a gold-catalyzed highly site-selective C(sp²)-H functionalization of unactivated arenes with α-aryl-α-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.

Original language	English
Pages (from-to)	10164-10167
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	73
DOIs	https://doi.org/10.1039/c7cc05649d
State	Published - 2017

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title = "Gold-catalyzed: Para -selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds",

abstract = "Herein, we report a gold-catalyzed highly site-selective C(sp2)-H functionalization of unactivated arenes with α-aryl-α-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.",

author = "Ben Ma and Jiaojiao Wu and Lu Liu and Junliang Zhang",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc05649d",

language = "英语",

volume = "53",

pages = "10164--10167",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Gold-catalyzed

T2 - Para -selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds

AU - Ma, Ben

AU - Wu, Jiaojiao

AU - Liu, Lu

AU - Zhang, Junliang

PY - 2017

Y1 - 2017

N2 - Herein, we report a gold-catalyzed highly site-selective C(sp2)-H functionalization of unactivated arenes with α-aryl-α-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.

AB - Herein, we report a gold-catalyzed highly site-selective C(sp2)-H functionalization of unactivated arenes with α-aryl-α-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.

UR - https://www.scopus.com/pages/publications/85029469296

U2 - 10.1039/c7cc05649d

DO - 10.1039/c7cc05649d

M3 - 文章

C2 - 28850128

AN - SCOPUS:85029469296

SN - 1359-7345

VL - 53

SP - 10164

EP - 10167

JO - Chemical Communications

JF - Chemical Communications

IS - 73

ER -

Gold-catalyzed: Para -selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds

Abstract

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