Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

Yao Rong Zheng; Brian H. Northrop; Hai Bo Yang; Liang Zhao; Peter J. Stang

doi:10.1021/jo9002932

Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

Yao Rong Zheng
, Brian H. Northrop
, Hai Bo Yang
, Liang Zhao
, Peter J. Stang

School of Chemistry and Molecular Engineering

University of Utah

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using ³¹P and ¹H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.

Original language	English
Pages (from-to)	3554-3557
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	74
Issue number	9
DOIs	https://doi.org/10.1021/jo9002932
State	Published - 1 May 2009

Access to Document

10.1021/jo9002932

Cite this

@article{c625fceff1084b75ab539303a7fe3ac4,

title = "Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons",

abstract = "The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using 31P and 1H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.",

author = "Zheng, \{Yao Rong\} and Northrop, \{Brian H.\} and Yang, \{Hai Bo\} and Liang Zhao and Stang, \{Peter J.\}",

year = "2009",

month = may,

day = "1",

doi = "10.1021/jo9002932",

language = "英语",

volume = "74",

pages = "3554--3557",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

AU - Zheng, Yao Rong

AU - Northrop, Brian H.

AU - Yang, Hai Bo

AU - Zhao, Liang

AU - Stang, Peter J.

PY - 2009/5/1

Y1 - 2009/5/1

N2 - The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using 31P and 1H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.

AB - The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using 31P and 1H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.

UR - https://www.scopus.com/pages/publications/66449099768

U2 - 10.1021/jo9002932

DO - 10.1021/jo9002932

M3 - 文章

C2 - 19348444

AN - SCOPUS:66449099768

SN - 0022-3263

VL - 74

SP - 3554

EP - 3557

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 9

ER -

Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

Abstract

Access to Document

Other files and links

Fingerprint

Cite this