Formation of 1,4,2-Dithiazolidines or 1,3-Thiazetidines from 1,1-Dichloro-2-nitroethene and Phenylthiourea Derivatives

Yian Feng; Minming Zou; Runjiang Song; Xusheng Shao; Zhong Li; Xuhong Qian

doi:10.1021/acs.joc.6b01307

Formation of 1,4,2-Dithiazolidines or 1,3-Thiazetidines from 1,1-Dichloro-2-nitroethene and Phenylthiourea Derivatives

Yian Feng
, Minming Zou
, Runjiang Song
, Xusheng Shao^*
, Zhong Li
, Xuhong Qian

^*Corresponding author for this work

East China University of Science and Technology
Shanghai Collaborative Innovation Center for Biomanufacturing (SCICB)

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A method for preparation of 1,4,2-dithiazolidine or 1,3-thiazetidine heterocycles was developed by reactions of phenylthioureas with 1,1-dichloro-2-nitroethene. The solvent has a significant influence on the type of product formation. 1,4,2-Dithiazolidines were formed in the aprotic solvent chloroform, while in the protic solvent ethanol, 1,3-thiazetidines were the main products.

Original language	English
Pages (from-to)	10321-10327
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	81
Issue number	21
DOIs	https://doi.org/10.1021/acs.joc.6b01307
State	Published - 4 Nov 2016
Externally published	Yes

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title = "Formation of 1,4,2-Dithiazolidines or 1,3-Thiazetidines from 1,1-Dichloro-2-nitroethene and Phenylthiourea Derivatives",

abstract = "A method for preparation of 1,4,2-dithiazolidine or 1,3-thiazetidine heterocycles was developed by reactions of phenylthioureas with 1,1-dichloro-2-nitroethene. The solvent has a significant influence on the type of product formation. 1,4,2-Dithiazolidines were formed in the aprotic solvent chloroform, while in the protic solvent ethanol, 1,3-thiazetidines were the main products.",

author = "Yian Feng and Minming Zou and Runjiang Song and Xusheng Shao and Zhong Li and Xuhong Qian",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = nov,

day = "4",

doi = "10.1021/acs.joc.6b01307",

language = "英语",

volume = "81",

pages = "10321--10327",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

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TY - JOUR

T1 - Formation of 1,4,2-Dithiazolidines or 1,3-Thiazetidines from 1,1-Dichloro-2-nitroethene and Phenylthiourea Derivatives

AU - Feng, Yian

AU - Zou, Minming

AU - Song, Runjiang

AU - Shao, Xusheng

AU - Li, Zhong

AU - Qian, Xuhong

PY - 2016/11/4

Y1 - 2016/11/4

N2 - A method for preparation of 1,4,2-dithiazolidine or 1,3-thiazetidine heterocycles was developed by reactions of phenylthioureas with 1,1-dichloro-2-nitroethene. The solvent has a significant influence on the type of product formation. 1,4,2-Dithiazolidines were formed in the aprotic solvent chloroform, while in the protic solvent ethanol, 1,3-thiazetidines were the main products.

AB - A method for preparation of 1,4,2-dithiazolidine or 1,3-thiazetidine heterocycles was developed by reactions of phenylthioureas with 1,1-dichloro-2-nitroethene. The solvent has a significant influence on the type of product formation. 1,4,2-Dithiazolidines were formed in the aprotic solvent chloroform, while in the protic solvent ethanol, 1,3-thiazetidines were the main products.

UR - https://www.scopus.com/pages/publications/84994607994

U2 - 10.1021/acs.joc.6b01307

DO - 10.1021/acs.joc.6b01307

M3 - 文章

AN - SCOPUS:84994607994

SN - 0022-3263

VL - 81

SP - 10321

EP - 10327

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Formation of 1,4,2-Dithiazolidines or 1,3-Thiazetidines from 1,1-Dichloro-2-nitroethene and Phenylthiourea Derivatives

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