Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide

Xiangqing Fang; Qiang Wang; Anmin Zheng; Yueming Liu; Yuning Wang; Xiujuan Deng; Haihong Wu; Feng Deng; Mingyuan He; Peng Wu

doi:10.1039/c2cy20446k

Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide

Xiangqing Fang
, Qiang Wang
, Anmin Zheng
, Yueming Liu^*
, Yuning Wang
, Xiujuan Deng
, Haihong Wu
, Feng Deng
, Mingyuan He
, Peng Wu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Fluorine species were successfully implanted into a MWW-type titanosilicate via post-treatment, which generates the SiO _3/2F units in the zeolite framework. The incorporated fluorine species significantly improved the catalytic performance in the epoxidation of alkenes as a result of enhancing the Lewis acid strength and the hydrophobicity of the zeolite.

Original language	English
Pages (from-to)	2433-2435
Number of pages	3
Journal	Catalysis Science and Technology
Volume	2
Issue number	12
DOIs	https://doi.org/10.1039/c2cy20446k
State	Published - Dec 2012

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title = "Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide",

abstract = "Fluorine species were successfully implanted into a MWW-type titanosilicate via post-treatment, which generates the SiO 3/2F units in the zeolite framework. The incorporated fluorine species significantly improved the catalytic performance in the epoxidation of alkenes as a result of enhancing the Lewis acid strength and the hydrophobicity of the zeolite.",

author = "Xiangqing Fang and Qiang Wang and Anmin Zheng and Yueming Liu and Yuning Wang and Xiujuan Deng and Haihong Wu and Feng Deng and Mingyuan He and Peng Wu",

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doi = "10.1039/c2cy20446k",

language = "英语",

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journal = "Catalysis Science and Technology",

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T1 - Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide

AU - Fang, Xiangqing

AU - Wang, Qiang

AU - Zheng, Anmin

AU - Liu, Yueming

AU - Wang, Yuning

AU - Deng, Xiujuan

AU - Wu, Haihong

AU - Deng, Feng

AU - He, Mingyuan

AU - Wu, Peng

PY - 2012/12

Y1 - 2012/12

N2 - Fluorine species were successfully implanted into a MWW-type titanosilicate via post-treatment, which generates the SiO 3/2F units in the zeolite framework. The incorporated fluorine species significantly improved the catalytic performance in the epoxidation of alkenes as a result of enhancing the Lewis acid strength and the hydrophobicity of the zeolite.

AB - Fluorine species were successfully implanted into a MWW-type titanosilicate via post-treatment, which generates the SiO 3/2F units in the zeolite framework. The incorporated fluorine species significantly improved the catalytic performance in the epoxidation of alkenes as a result of enhancing the Lewis acid strength and the hydrophobicity of the zeolite.

UR - https://www.scopus.com/pages/publications/84868679905

U2 - 10.1039/c2cy20446k

DO - 10.1039/c2cy20446k

M3 - 文章

AN - SCOPUS:84868679905

SN - 2044-4753

VL - 2

SP - 2433

EP - 2435

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 12

ER -

Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide

Abstract

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