TY - JOUR
T1 - Fighting at the Interface
T2 - Structural Evolution during Heteroepitaxial Growth of Cyanometallate Coordination Polymers
AU - Li, Fengqiong
AU - Zhang, Wei
AU - Carné-Sánchez, Arnau
AU - Tsujimoto, Yoshihiro
AU - Kitagawa, Susumu
AU - Furukawa, Shuhei
AU - Hu, Ming
N1 - Publisher Copyright:
Copyright © 2018 American Chemical Society.
PY - 2018/8/6
Y1 - 2018/8/6
N2 - Hybridization of coordination polymers allows for combining two or more distinct structures into one material. Here, we explore the core/shell-type materials of Prussian blue analogues (PBAs) by heteroepitaxial growth and demonstrate how one phase structurally dominates the other. The volumetric ratio between the shell and core crystals determine the final structure of the hybrids. The outermost dominated the Na+ ion insertion/extraction, illustrating how the hybridization can adjust the function of PBAs.
AB - Hybridization of coordination polymers allows for combining two or more distinct structures into one material. Here, we explore the core/shell-type materials of Prussian blue analogues (PBAs) by heteroepitaxial growth and demonstrate how one phase structurally dominates the other. The volumetric ratio between the shell and core crystals determine the final structure of the hybrids. The outermost dominated the Na+ ion insertion/extraction, illustrating how the hybridization can adjust the function of PBAs.
UR - https://www.scopus.com/pages/publications/85051194266
U2 - 10.1021/acs.inorgchem.8b00959
DO - 10.1021/acs.inorgchem.8b00959
M3 - 文章
C2 - 30024158
AN - SCOPUS:85051194266
SN - 0020-1669
VL - 57
SP - 8701
EP - 8704
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 15
ER -