Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N-H bonds

Minghong Zhou; Hui Zhang; Linfeng Xiong; Zidong He; Tianqi Wang; Yang Xu; Kun Huang

doi:10.1039/c7py00530j

Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N-H bonds

Minghong Zhou
, Hui Zhang
, Linfeng Xiong
, Zidong He
, Tianqi Wang
, Yang Xu
, Kun Huang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Novel meso-tetraphenylporphyrin iron(iii) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core-shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N-H bonds with ethyl diazoacetate.

Original language	English
Pages (from-to)	3721-3730
Number of pages	10
Journal	Polymer Chemistry
Volume	8
Issue number	24
DOIs	https://doi.org/10.1039/c7py00530j
State	Published - 28 Jun 2017

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title = "Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N-H bonds",

abstract = "Novel meso-tetraphenylporphyrin iron(iii) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core-shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N-H bonds with ethyl diazoacetate.",

author = "Minghong Zhou and Hui Zhang and Linfeng Xiong and Zidong He and Tianqi Wang and Yang Xu and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

month = jun,

day = "28",

doi = "10.1039/c7py00530j",

language = "英语",

volume = "8",

pages = "3721--3730",

journal = "Polymer Chemistry",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N-H bonds

AU - Zhou, Minghong

AU - Zhang, Hui

AU - Xiong, Linfeng

AU - He, Zidong

AU - Wang, Tianqi

AU - Xu, Yang

AU - Huang, Kun

PY - 2017/6/28

Y1 - 2017/6/28

N2 - Novel meso-tetraphenylporphyrin iron(iii) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core-shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N-H bonds with ethyl diazoacetate.

AB - Novel meso-tetraphenylporphyrin iron(iii) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core-shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N-H bonds with ethyl diazoacetate.

UR - https://www.scopus.com/pages/publications/85021718610

U2 - 10.1039/c7py00530j

DO - 10.1039/c7py00530j

M3 - 文章

AN - SCOPUS:85021718610

SN - 1759-9954

VL - 8

SP - 3721

EP - 3730

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 24

ER -

Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N-H bonds

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