Fast mechanochemical synthesis of nano-structured PMN at low temperature

  • Hao Wu*
  • , Cheng Chen
  • , Dan Yu Jiang
  • , Qiang Li
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Nanoscale lead magnesium niobate(PMN)powders of perovskite phase were synthesized by the screw grinder for 3h starting from raw materials of oxides. The influences of reaction conditions on products, such as weight of raw materials, grind power and grind time, were studied in detail. The results show that high grind power can reduce the synthesis time, improve the purity of products and decrease the particle size. The mechanochemical mechanism of PMN synthesis is confirmed via cross reaction experiments between raw materials. Magnesium niobate is firstly formed through mechanochemical reaction between MgO and Nb2O5, then reacted with PbO to get the PMN finally.

Original languageEnglish
Pages (from-to)541-545
Number of pages5
JournalWuji Cailiao Xuebao/Journal of Inorganic Materials
Volume25
Issue number5
DOIs
StatePublished - May 2010

Keywords

  • Lead magnesium niobate
  • Mechanochemical synthesis
  • Reaction mechanism

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