Fast Lithium-Ion Transportation in Crystalline Polymer Electrolytes

Xiao Bin Fu; Guang Yang; Jin Ze Wu; Jia Chen Wang; Qun Chen; Ye Feng Yao

doi:10.1002/cphc.201701092

Fast Lithium-Ion Transportation in Crystalline Polymer Electrolytes

Xiao Bin Fu
, Guang Yang
, Jin Ze Wu
, Jia Chen Wang
, Qun Chen
, Ye Feng Yao^*

^*Corresponding author for this work

School of Physics and Electronic Science

East China Normal University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Fast lithium-ion transportation is found in the crystalline polymer electrolytes, α-CD-PEO_n/Li⁺ (n=12, 40), prepared by self-assembly of α-cyclodextrin (CD), polyethylene oxide (PEO) and Li⁺ salts. A detailed solid-state NMR study combined with the X-ray diffraction technique reveals the unique structural features of the samples, that is, a) the tunnel structure formed by the assembled CDs, providing the ordered long-range pathway for Li⁺ ion transportation; b) the all-trans conformational sequence of the PEO chains in the tunnels, attenuating significantly the coordination between Li⁺ and the EO segments. The origin of the fast lithium-ion transportation has been attributed to these unique structural features. This work demonstrates the first example in solid polymer electrolytes (SPEs) for “creating” fast ion transportation through material design and will find potential applications in the design of new ionconducting SPE materials.

Original language	English
Pages (from-to)	45-50
Number of pages	6
Journal	ChemPhysChem
Volume	19
Issue number	1
DOIs	https://doi.org/10.1002/cphc.201701092
State	Published - 5 Jan 2018

Keywords

fast ion transportation
inclusion compounds
molecular dynamics
polymer electrolytes
solid-state NMR spectroscopy

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10.1002/cphc.201701092

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title = "Fast Lithium-Ion Transportation in Crystalline Polymer Electrolytes",

abstract = "Fast lithium-ion transportation is found in the crystalline polymer electrolytes, α-CD-PEOn/Li+ (n=12, 40), prepared by self-assembly of α-cyclodextrin (CD), polyethylene oxide (PEO) and Li+ salts. A detailed solid-state NMR study combined with the X-ray diffraction technique reveals the unique structural features of the samples, that is, a) the tunnel structure formed by the assembled CDs, providing the ordered long-range pathway for Li+ ion transportation; b) the all-trans conformational sequence of the PEO chains in the tunnels, attenuating significantly the coordination between Li+ and the EO segments. The origin of the fast lithium-ion transportation has been attributed to these unique structural features. This work demonstrates the first example in solid polymer electrolytes (SPEs) for “creating” fast ion transportation through material design and will find potential applications in the design of new ionconducting SPE materials.",

keywords = "fast ion transportation, inclusion compounds, molecular dynamics, polymer electrolytes, solid-state NMR spectroscopy",

author = "Fu, \{Xiao Bin\} and Guang Yang and Wu, \{Jin Ze\} and Wang, \{Jia Chen\} and Qun Chen and Yao, \{Ye Feng\}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = jan,

day = "5",

doi = "10.1002/cphc.201701092",

language = "英语",

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journal = "ChemPhysChem",

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T1 - Fast Lithium-Ion Transportation in Crystalline Polymer Electrolytes

AU - Fu, Xiao Bin

AU - Yang, Guang

AU - Wu, Jin Ze

AU - Wang, Jia Chen

AU - Chen, Qun

AU - Yao, Ye Feng

PY - 2018/1/5

Y1 - 2018/1/5

N2 - Fast lithium-ion transportation is found in the crystalline polymer electrolytes, α-CD-PEOn/Li+ (n=12, 40), prepared by self-assembly of α-cyclodextrin (CD), polyethylene oxide (PEO) and Li+ salts. A detailed solid-state NMR study combined with the X-ray diffraction technique reveals the unique structural features of the samples, that is, a) the tunnel structure formed by the assembled CDs, providing the ordered long-range pathway for Li+ ion transportation; b) the all-trans conformational sequence of the PEO chains in the tunnels, attenuating significantly the coordination between Li+ and the EO segments. The origin of the fast lithium-ion transportation has been attributed to these unique structural features. This work demonstrates the first example in solid polymer electrolytes (SPEs) for “creating” fast ion transportation through material design and will find potential applications in the design of new ionconducting SPE materials.

AB - Fast lithium-ion transportation is found in the crystalline polymer electrolytes, α-CD-PEOn/Li+ (n=12, 40), prepared by self-assembly of α-cyclodextrin (CD), polyethylene oxide (PEO) and Li+ salts. A detailed solid-state NMR study combined with the X-ray diffraction technique reveals the unique structural features of the samples, that is, a) the tunnel structure formed by the assembled CDs, providing the ordered long-range pathway for Li+ ion transportation; b) the all-trans conformational sequence of the PEO chains in the tunnels, attenuating significantly the coordination between Li+ and the EO segments. The origin of the fast lithium-ion transportation has been attributed to these unique structural features. This work demonstrates the first example in solid polymer electrolytes (SPEs) for “creating” fast ion transportation through material design and will find potential applications in the design of new ionconducting SPE materials.

KW - fast ion transportation

KW - inclusion compounds

KW - molecular dynamics

KW - polymer electrolytes

KW - solid-state NMR spectroscopy

UR - https://www.scopus.com/pages/publications/85034789708

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DO - 10.1002/cphc.201701092

M3 - 文章

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SN - 1439-4235

VL - 19

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EP - 50

JO - ChemPhysChem

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IS - 1

ER -

Fast Lithium-Ion Transportation in Crystalline Polymer Electrolytes

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Keywords

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