Facile synthesis of nanoporous hydroquinone/catechol formaldehyde resins and their highly selective, efficient and regenerate reactive adsorption for gold ions

Shaozhong Zeng; Limin Guo; Lingxia Zhang; Fangming Cui; Jian Zhou; Zhe Gao; Yu Chen; Jianlin Shi

doi:10.1002/macp.200900534

Facile synthesis of nanoporous hydroquinone/catechol formaldehyde resins and their highly selective, efficient and regenerate reactive adsorption for gold ions

Shaozhong Zeng, Limin Guo, Lingxia Zhang, Fangming Cui, Jian Zhou, Zhe Gao, Yu Chen, Jianlin Shi

CAS - Shanghai Institute of Ceramics

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

We present a new type of nanoporous hydroquinone/catechol formaldehyde resin synthesized by a one-pot route, with a surface area of up to 1 112m ² . g^-1. The resins show highly efficient reactive adsorption for silver/gold (silver adsorbance up to 2.43 g . g^-1) and excellent selectivity for gold (K_d is as high as 1 914 090mL. g ^-1). The first-used resins can be regenerated with NaHSO₃, and the gold capacities of the recycled PCFR and PHFR reach 44 and 78% of their first loading capacities, respectively.

Original language	English
Pages (from-to)	845-853
Number of pages	9
Journal	Macromolecular Chemistry and Physics
Volume	211
Issue number	8
DOIs	https://doi.org/10.1002/macp.200900534
State	Published - 15 Apr 2010
Externally published	Yes

Keywords

Hypercrosslinked
Porous polymers
Reactive adsorption
Synthesis

Access to Document

10.1002/macp.200900534

Cite this

@article{8f1698edb5a14a51bd95c7cf50cefe9e,

title = "Facile synthesis of nanoporous hydroquinone/catechol formaldehyde resins and their highly selective, efficient and regenerate reactive adsorption for gold ions",

abstract = "We present a new type of nanoporous hydroquinone/catechol formaldehyde resin synthesized by a one-pot route, with a surface area of up to 1 112m 2 . g-1. The resins show highly efficient reactive adsorption for silver/gold (silver adsorbance up to 2.43 g . g-1) and excellent selectivity for gold (Kd is as high as 1 914 090mL. g -1). The first-used resins can be regenerated with NaHSO3, and the gold capacities of the recycled PCFR and PHFR reach 44 and 78\% of their first loading capacities, respectively.",

keywords = "Hypercrosslinked, Porous polymers, Reactive adsorption, Synthesis",

author = "Shaozhong Zeng and Limin Guo and Lingxia Zhang and Fangming Cui and Jian Zhou and Zhe Gao and Yu Chen and Jianlin Shi",

year = "2010",

month = apr,

day = "15",

doi = "10.1002/macp.200900534",

language = "英语",

volume = "211",

pages = "845--853",

journal = "Macromolecular Chemistry and Physics",

issn = "1022-1352",

publisher = "Wiley-VCH Verlag",

number = "8",

}

TY - JOUR

T1 - Facile synthesis of nanoporous hydroquinone/catechol formaldehyde resins and their highly selective, efficient and regenerate reactive adsorption for gold ions

AU - Zeng, Shaozhong

AU - Guo, Limin

AU - Zhang, Lingxia

AU - Cui, Fangming

AU - Zhou, Jian

AU - Gao, Zhe

AU - Chen, Yu

AU - Shi, Jianlin

PY - 2010/4/15

Y1 - 2010/4/15

N2 - We present a new type of nanoporous hydroquinone/catechol formaldehyde resin synthesized by a one-pot route, with a surface area of up to 1 112m 2 . g-1. The resins show highly efficient reactive adsorption for silver/gold (silver adsorbance up to 2.43 g . g-1) and excellent selectivity for gold (Kd is as high as 1 914 090mL. g -1). The first-used resins can be regenerated with NaHSO3, and the gold capacities of the recycled PCFR and PHFR reach 44 and 78% of their first loading capacities, respectively.

AB - We present a new type of nanoporous hydroquinone/catechol formaldehyde resin synthesized by a one-pot route, with a surface area of up to 1 112m 2 . g-1. The resins show highly efficient reactive adsorption for silver/gold (silver adsorbance up to 2.43 g . g-1) and excellent selectivity for gold (Kd is as high as 1 914 090mL. g -1). The first-used resins can be regenerated with NaHSO3, and the gold capacities of the recycled PCFR and PHFR reach 44 and 78% of their first loading capacities, respectively.

KW - Hypercrosslinked

KW - Porous polymers

KW - Reactive adsorption

KW - Synthesis

UR - https://www.scopus.com/pages/publications/77951606836

U2 - 10.1002/macp.200900534

DO - 10.1002/macp.200900534

M3 - 文章

AN - SCOPUS:77951606836

SN - 1022-1352

VL - 211

SP - 845

EP - 853

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 8

ER -

Facile synthesis of nanoporous hydroquinone/catechol formaldehyde resins and their highly selective, efficient and regenerate reactive adsorption for gold ions

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this