Facile fabrication of a silver dendrite-integrated chip for surface-enhanced Raman scattering

Hai Xin Gu; Lin Xue; Yong Feng Zhang; Da Wei Li; Yi Tao Long

doi:10.1021/am508403k

Facile fabrication of a silver dendrite-integrated chip for surface-enhanced Raman scattering

Hai Xin Gu
, Lin Xue
, Yong Feng Zhang
, Da Wei Li
, Yi Tao Long^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A facile approach to fabricating a surface-enhanced Raman scattering (SERS)-active chip by integrating silver dendrites with copper substrate through a one-step process was explored. The structures of dendrites were synthesized and controlled by an AgNO₃/PVP aqueous system, and the fabrication parameters amount of AgNO₃/PVP and reaction time were systematically investigated. The optimized silver dendrites, closely aggregated on the surface of the copper chip, exhibited high SERS activity for detecting rhodamine 6G at a concentration as low as 3.2 × 10^-11 M. Meanwhile, the prepared SERS-active chip displayed a high thermal stability and good reproducibility. Moreover, the potential application for analysis of polycyclic aromatic hydrocarbons was demonstrated by detection of fluoranthene at a low concentration of 4.5 × 10^-10 M. This SERS-active chip prepared by the convenient and high-yield method would be a promising means for rapid detection under field conditions.

Original language	English
Pages (from-to)	2931-2936
Number of pages	6
Journal	ACS Applied Materials and Interfaces
Volume	7
Issue number	4
DOIs	https://doi.org/10.1021/am508403k
State	Published - 4 Feb 2015
Externally published	Yes

Keywords

SERS
copper substrate
detection chip
silver dendrites

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10.1021/am508403k

Cite this

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title = "Facile fabrication of a silver dendrite-integrated chip for surface-enhanced Raman scattering",

abstract = "A facile approach to fabricating a surface-enhanced Raman scattering (SERS)-active chip by integrating silver dendrites with copper substrate through a one-step process was explored. The structures of dendrites were synthesized and controlled by an AgNO3/PVP aqueous system, and the fabrication parameters amount of AgNO3/PVP and reaction time were systematically investigated. The optimized silver dendrites, closely aggregated on the surface of the copper chip, exhibited high SERS activity for detecting rhodamine 6G at a concentration as low as 3.2 × 10-11 M. Meanwhile, the prepared SERS-active chip displayed a high thermal stability and good reproducibility. Moreover, the potential application for analysis of polycyclic aromatic hydrocarbons was demonstrated by detection of fluoranthene at a low concentration of 4.5 × 10-10 M. This SERS-active chip prepared by the convenient and high-yield method would be a promising means for rapid detection under field conditions.",

keywords = "SERS, copper substrate, detection chip, silver dendrites",

author = "Gu, \{Hai Xin\} and Lin Xue and Zhang, \{Yong Feng\} and Li, \{Da Wei\} and Long, \{Yi Tao\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = feb,

day = "4",

doi = "10.1021/am508403k",

language = "英语",

volume = "7",

pages = "2931--2936",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Facile fabrication of a silver dendrite-integrated chip for surface-enhanced Raman scattering

AU - Gu, Hai Xin

AU - Xue, Lin

AU - Zhang, Yong Feng

AU - Li, Da Wei

AU - Long, Yi Tao

PY - 2015/2/4

Y1 - 2015/2/4

N2 - A facile approach to fabricating a surface-enhanced Raman scattering (SERS)-active chip by integrating silver dendrites with copper substrate through a one-step process was explored. The structures of dendrites were synthesized and controlled by an AgNO3/PVP aqueous system, and the fabrication parameters amount of AgNO3/PVP and reaction time were systematically investigated. The optimized silver dendrites, closely aggregated on the surface of the copper chip, exhibited high SERS activity for detecting rhodamine 6G at a concentration as low as 3.2 × 10-11 M. Meanwhile, the prepared SERS-active chip displayed a high thermal stability and good reproducibility. Moreover, the potential application for analysis of polycyclic aromatic hydrocarbons was demonstrated by detection of fluoranthene at a low concentration of 4.5 × 10-10 M. This SERS-active chip prepared by the convenient and high-yield method would be a promising means for rapid detection under field conditions.

AB - A facile approach to fabricating a surface-enhanced Raman scattering (SERS)-active chip by integrating silver dendrites with copper substrate through a one-step process was explored. The structures of dendrites were synthesized and controlled by an AgNO3/PVP aqueous system, and the fabrication parameters amount of AgNO3/PVP and reaction time were systematically investigated. The optimized silver dendrites, closely aggregated on the surface of the copper chip, exhibited high SERS activity for detecting rhodamine 6G at a concentration as low as 3.2 × 10-11 M. Meanwhile, the prepared SERS-active chip displayed a high thermal stability and good reproducibility. Moreover, the potential application for analysis of polycyclic aromatic hydrocarbons was demonstrated by detection of fluoranthene at a low concentration of 4.5 × 10-10 M. This SERS-active chip prepared by the convenient and high-yield method would be a promising means for rapid detection under field conditions.

KW - SERS

KW - copper substrate

KW - detection chip

KW - silver dendrites

UR - https://www.scopus.com/pages/publications/84922439163

U2 - 10.1021/am508403k

DO - 10.1021/am508403k

M3 - 文章

AN - SCOPUS:84922439163

SN - 1944-8244

VL - 7

SP - 2931

EP - 2936

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 4

ER -

Facile fabrication of a silver dendrite-integrated chip for surface-enhanced Raman scattering

Abstract

Keywords

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