Fabrication of core@shell structural Fe-Fe₂O₃@PHCP nanochains with high saturation magnetization and abundant amino groups for hexavalent chromium adsorption and reduction

The rational design of novel adsorption materials is imperative to remove toxic metal species from the polluted water. Herein, a core@shell structural Fe-Fe₂O₃@poly (hexachlorocyclotriphosphazene-co-polyethylenimine) (Fe-Fe₂O₃@PHCP) magnetic nanochain with high saturation magnetization was fabricated and used for effective adsorption and reduction of hexavalent chromium. The morphology and microstructure of Fe-Fe₂O₃@PHCP were characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy. The effects of concentration, pH, contact time, temperature and coexisting ions on Cr (VI) removal were studied. Four kinetic models (pseudo-first-order, pseudo-second-order, Bangham and intraparticle diffusion models) and two isotherm models (Freundlich and Langmuir) were used to fit experimental data. Results show the adsorption capacity of Fe-Fe₂O₃@PHCP for Cr (VI) is up to 229.0 mg g⁻¹. The excellent performance was ascribed to the favorable reduction of Cr (VI) to Cr (III), followed by the chelation of Cr (III) with imino groups. Meanwhile, the residual Cr (VI) were adsorbed on protonated amino and imino groups. The adsorption process is exothermic and spontaneous and nicely follows pseudo-second-order kinetics, intraparticle diffusion model and Langmuir isotherm model. These results indicated that easily separable Fe-Fe₂O₃@PHCP magnetic nanochains could be a promising adsorbent to remediate chromate wastewater.