Fabrication and characteristics of porous germanium films

Chengbin Jing*, Chuanjian Zhang, Xiaodan Zang, Wenzheng Zhou, Wei Bai, Tie Lin, Junhao Chu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Porous germanium films with good adhesion to the substrate were produced by annealing GeO2 ceramic films in H2 atmosphere. The reduction of GeO2 started at the top of a film and resulted in a Ge layer with a highly porous surface. TEM and Raman measurements reveal small Ge crystallites at the top layer and a higher degree of crystallinity at the bottom part of the Ge film; visible photoluminescence was detected from the small crystallites. Porous Ge films exhibit high density of holes (1020 cm-3) and a maximum of Hall mobility at ∼225 K. Their p-type conductivity is dominated by the defect scattering mechanism.

Original languageEnglish
Article number065001
JournalScience and Technology of Advanced Materials
Volume10
Issue number6
DOIs
StatePublished - 2009
Externally publishedYes

Keywords

  • Germanium
  • Porous structured film
  • Semiconducting behavior
  • Visible photoluminescence

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