Exploring the Capacity Limit: A Layered Hexacarboxylate-Based Metal-Organic Framework for Advanced Lithium Storage

Xiaobing Lou; Yanqun Ning; Chao Li; Ming Shen; Bei Hu; Xiaoshi Hu; Bingwen Hu

doi:10.1021/acs.inorgchem.7b02939

Exploring the Capacity Limit: A Layered Hexacarboxylate-Based Metal-Organic Framework for Advanced Lithium Storage

Xiaobing Lou
, Yanqun Ning
, Chao Li
, Ming Shen
, Bei Hu
, Xiaoshi Hu
, Bingwen Hu^*

^*Corresponding author for this work

East China Normal University

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Our previous work suggested that more carboxylate groups might lead to higher energy density for metal-organic frameworks. In this study, we synthesized a layered metal-organic framework (MOF) Ni-BHC by use of 1,2,3,4,5,6-benzenehexacarboxylic acid. After evacuation by thermal treatment, this MOF was employed as an anode for lithium storage. For its rich lithiation sites as well as layered fast-kinetics structure, it delivers a superior reversible capacity of 1261.3 mA h g^-1 at 100 mA g^-1, far exceeding the performance of previously reported MOF-based anode materials. Density functional theory calculation and O soft X-ray absorption spectroscopy suggest that the luxuriant carboxylate-metal units play an important part in the electrochemical process.

Original language	English
Pages (from-to)	3126-3132
Number of pages	7
Journal	Inorganic Chemistry
Volume	57
Issue number	6
DOIs	https://doi.org/10.1021/acs.inorgchem.7b02939
State	Published - 19 Mar 2018
Externally published	Yes

Access to Document

10.1021/acs.inorgchem.7b02939

Cite this

@article{4607cacd87ea4ee1b9182ae424807715,

title = "Exploring the Capacity Limit: A Layered Hexacarboxylate-Based Metal-Organic Framework for Advanced Lithium Storage",

abstract = "Our previous work suggested that more carboxylate groups might lead to higher energy density for metal-organic frameworks. In this study, we synthesized a layered metal-organic framework (MOF) Ni-BHC by use of 1,2,3,4,5,6-benzenehexacarboxylic acid. After evacuation by thermal treatment, this MOF was employed as an anode for lithium storage. For its rich lithiation sites as well as layered fast-kinetics structure, it delivers a superior reversible capacity of 1261.3 mA h g-1 at 100 mA g-1, far exceeding the performance of previously reported MOF-based anode materials. Density functional theory calculation and O soft X-ray absorption spectroscopy suggest that the luxuriant carboxylate-metal units play an important part in the electrochemical process.",

author = "Xiaobing Lou and Yanqun Ning and Chao Li and Ming Shen and Bei Hu and Xiaoshi Hu and Bingwen Hu",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = mar,

day = "19",

doi = "10.1021/acs.inorgchem.7b02939",

language = "英语",

volume = "57",

pages = "3126--3132",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Exploring the Capacity Limit

T2 - A Layered Hexacarboxylate-Based Metal-Organic Framework for Advanced Lithium Storage

AU - Lou, Xiaobing

AU - Ning, Yanqun

AU - Li, Chao

AU - Shen, Ming

AU - Hu, Bei

AU - Hu, Xiaoshi

AU - Hu, Bingwen

PY - 2018/3/19

Y1 - 2018/3/19

N2 - Our previous work suggested that more carboxylate groups might lead to higher energy density for metal-organic frameworks. In this study, we synthesized a layered metal-organic framework (MOF) Ni-BHC by use of 1,2,3,4,5,6-benzenehexacarboxylic acid. After evacuation by thermal treatment, this MOF was employed as an anode for lithium storage. For its rich lithiation sites as well as layered fast-kinetics structure, it delivers a superior reversible capacity of 1261.3 mA h g-1 at 100 mA g-1, far exceeding the performance of previously reported MOF-based anode materials. Density functional theory calculation and O soft X-ray absorption spectroscopy suggest that the luxuriant carboxylate-metal units play an important part in the electrochemical process.

AB - Our previous work suggested that more carboxylate groups might lead to higher energy density for metal-organic frameworks. In this study, we synthesized a layered metal-organic framework (MOF) Ni-BHC by use of 1,2,3,4,5,6-benzenehexacarboxylic acid. After evacuation by thermal treatment, this MOF was employed as an anode for lithium storage. For its rich lithiation sites as well as layered fast-kinetics structure, it delivers a superior reversible capacity of 1261.3 mA h g-1 at 100 mA g-1, far exceeding the performance of previously reported MOF-based anode materials. Density functional theory calculation and O soft X-ray absorption spectroscopy suggest that the luxuriant carboxylate-metal units play an important part in the electrochemical process.

UR - https://www.scopus.com/pages/publications/85044215803

U2 - 10.1021/acs.inorgchem.7b02939

DO - 10.1021/acs.inorgchem.7b02939

M3 - 文章

C2 - 29485274

AN - SCOPUS:85044215803

SN - 0020-1669

VL - 57

SP - 3126

EP - 3132

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Exploring the Capacity Limit: A Layered Hexacarboxylate-Based Metal-Organic Framework for Advanced Lithium Storage

Abstract

Access to Document

Other files and links

Fingerprint

Cite this