Experimental study on photoionization of 1,3,5-trimethylbenzene

Ling Tao; Ming Qiang Huang; Wei Jun Zhang; Zhen Ya Wang; Wen Zheng Fang; Xiao Bin Shan; Fu Yi Liu; Liu Si Sheng

Experimental study on photoionization of 1,3,5-trimethylbenzene

Ling Tao
, Ming Qiang Huang
, Wei Jun Zhang^*
, Zhen Ya Wang
, Wen Zheng Fang
, Xiao Bin Shan
, Fu Yi Liu
, Liu Si Sheng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The photoionization and dissociation of 1,3,5-trimethylbenzene (TMB, C₉H₁₂) have been obtained using supersonic molecule beam, synchrotron radiation and photoionization mass spectrometry (PIMS). The photoionization efficiency (PIE) curves of the parent ion and some fragment ions were measured. The ionization energy (IE) of TMB and the appearance energies (AEs) of C₉H₁₁⁺ and C₈H₉⁺ were measured to be (8.32±0.03), (11.71±0.03) and (11.59±0.03) eV respectively. The dissociation energies (E_d) to produce C₉H₁₁⁺ and C₈H₉⁺ were deduced to be (3.39±0.06) and (3.27±0.06) eV respectively. The formation enthalpies of C₉H₁₂⁺, C₉H₁₁⁺ and C₈H₉⁺ were also deduced to be 786.87, 897.93 and 956.68 kJ/mol respectively.

Original language	English
Pages (from-to)	2059-2062
Number of pages	4
Journal	Acta Chimica Sinica
Volume	68
Issue number	20
State	Published - 28 Oct 2010
Externally published	Yes

Keywords

1,3,5-trimethylbenzene
Dissociative photoionization
Photoionization mass spectrometry
Synchrotron radiation

Cite this

@article{1361930d29cd49b381ac15829939d9a7,

title = "Experimental study on photoionization of 1,3,5-trimethylbenzene",

abstract = "The photoionization and dissociation of 1,3,5-trimethylbenzene (TMB, C9H12) have been obtained using supersonic molecule beam, synchrotron radiation and photoionization mass spectrometry (PIMS). The photoionization efficiency (PIE) curves of the parent ion and some fragment ions were measured. The ionization energy (IE) of TMB and the appearance energies (AEs) of C9H11+ and C8H9+ were measured to be (8.32±0.03), (11.71±0.03) and (11.59±0.03) eV respectively. The dissociation energies (Ed) to produce C9H11+ and C8H9+ were deduced to be (3.39±0.06) and (3.27±0.06) eV respectively. The formation enthalpies of C9H12+, C9H11+ and C8H9+ were also deduced to be 786.87, 897.93 and 956.68 kJ/mol respectively.",

keywords = "1,3,5-trimethylbenzene, Dissociative photoionization, Photoionization mass spectrometry, Synchrotron radiation",

author = "Ling Tao and Huang, \{Ming Qiang\} and Zhang, \{Wei Jun\} and Wang, \{Zhen Ya\} and Fang, \{Wen Zheng\} and Shan, \{Xiao Bin\} and Liu, \{Fu Yi\} and Sheng, \{Liu Si\}",

year = "2010",

month = oct,

day = "28",

language = "英语",

volume = "68",

pages = "2059--2062",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Editorial Office of Acta Chimica Sinica",

number = "20",

}

TY - JOUR

T1 - Experimental study on photoionization of 1,3,5-trimethylbenzene

AU - Tao, Ling

AU - Huang, Ming Qiang

AU - Zhang, Wei Jun

AU - Wang, Zhen Ya

AU - Fang, Wen Zheng

AU - Shan, Xiao Bin

AU - Liu, Fu Yi

AU - Sheng, Liu Si

PY - 2010/10/28

Y1 - 2010/10/28

N2 - The photoionization and dissociation of 1,3,5-trimethylbenzene (TMB, C9H12) have been obtained using supersonic molecule beam, synchrotron radiation and photoionization mass spectrometry (PIMS). The photoionization efficiency (PIE) curves of the parent ion and some fragment ions were measured. The ionization energy (IE) of TMB and the appearance energies (AEs) of C9H11+ and C8H9+ were measured to be (8.32±0.03), (11.71±0.03) and (11.59±0.03) eV respectively. The dissociation energies (Ed) to produce C9H11+ and C8H9+ were deduced to be (3.39±0.06) and (3.27±0.06) eV respectively. The formation enthalpies of C9H12+, C9H11+ and C8H9+ were also deduced to be 786.87, 897.93 and 956.68 kJ/mol respectively.

AB - The photoionization and dissociation of 1,3,5-trimethylbenzene (TMB, C9H12) have been obtained using supersonic molecule beam, synchrotron radiation and photoionization mass spectrometry (PIMS). The photoionization efficiency (PIE) curves of the parent ion and some fragment ions were measured. The ionization energy (IE) of TMB and the appearance energies (AEs) of C9H11+ and C8H9+ were measured to be (8.32±0.03), (11.71±0.03) and (11.59±0.03) eV respectively. The dissociation energies (Ed) to produce C9H11+ and C8H9+ were deduced to be (3.39±0.06) and (3.27±0.06) eV respectively. The formation enthalpies of C9H12+, C9H11+ and C8H9+ were also deduced to be 786.87, 897.93 and 956.68 kJ/mol respectively.

KW - 1,3,5-trimethylbenzene

KW - Dissociative photoionization

KW - Photoionization mass spectrometry

KW - Synchrotron radiation

UR - https://www.scopus.com/pages/publications/84884684077

M3 - 文章

AN - SCOPUS:84884684077

SN - 0567-7351

VL - 68

SP - 2059

EP - 2062

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 20

ER -

Experimental study on photoionization of 1,3,5-trimethylbenzene

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