Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction

Min Hou; Mengmeng Xu; Baochao Yang; Haibing He; Shuanhu Gao

doi:10.1021/acs.orglett.1c02719

Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction

Min Hou
, Mengmeng Xu
, Baochao Yang
, Haibing He^*
, Shuanhu Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

An unusual exo-selective photoenolization/Diels-Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its α position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.

Original language	English
Pages (from-to)	7487-7491
Number of pages	5
Journal	Organic Letters
Volume	23
Issue number	19
DOIs	https://doi.org/10.1021/acs.orglett.1c02719
State	Published - 1 Oct 2021

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10.1021/acs.orglett.1c02719

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title = "Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction",

abstract = "An unusual exo-selective photoenolization/Diels-Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its α position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.",

author = "Min Hou and Mengmeng Xu and Baochao Yang and Haibing He and Shuanhu Gao",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

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T1 - Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction

AU - Hou, Min

AU - Xu, Mengmeng

AU - Yang, Baochao

AU - He, Haibing

AU - Gao, Shuanhu

PY - 2021/10/1

Y1 - 2021/10/1

N2 - An unusual exo-selective photoenolization/Diels-Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its α position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.

AB - An unusual exo-selective photoenolization/Diels-Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its α position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.

UR - https://www.scopus.com/pages/publications/85116548409

U2 - 10.1021/acs.orglett.1c02719

DO - 10.1021/acs.orglett.1c02719

M3 - 文章

C2 - 34550708

AN - SCOPUS:85116548409

SN - 1523-7060

VL - 23

SP - 7487

EP - 7491

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction

Abstract

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