Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System

Ningning LI; Yueming LIU; Haihong WU; Xiaohong LI; Wei XIE; Zhonglin ZHAO; Peng WU; Mingyuan HE

doi:10.1016/S1872-2067(08)60018-2

Epoxidation of Various Functionalized Olefins by a Ti-MWW/H₂O₂ Catalytic System

Ningning LI
, Yueming LIU
, Haihong WU
, Xiaohong LI
, Wei XIE
, Zhonglin ZHAO
, Peng WU^*
, Mingyuan HE

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

Original language	English
Pages (from-to)	102-104
Number of pages	3
Journal	Chinese Journal of Catalysis
Volume	29
Issue number	2
DOIs	https://doi.org/10.1016/S1872-2067(08)60018-2
State	Published - Feb 2008

Keywords

TS-1
Ti-MWW
epoxidation
functionalized olefin

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10.1016/S1872-2067(08)60018-2

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title = "Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System",

abstract = "The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.",

keywords = "TS-1, Ti-MWW, epoxidation, functionalized olefin",

author = "Ningning LI and Yueming LIU and Haihong WU and Xiaohong LI and Wei XIE and Zhonglin ZHAO and Peng WU and Mingyuan HE",

year = "2008",

month = feb,

doi = "10.1016/S1872-2067(08)60018-2",

language = "英语",

volume = "29",

pages = "102--104",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press ",

number = "2",

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TY - JOUR

T1 - Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System

AU - LI, Ningning

AU - LIU, Yueming

AU - WU, Haihong

AU - LI, Xiaohong

AU - XIE, Wei

AU - ZHAO, Zhonglin

AU - WU, Peng

AU - HE, Mingyuan

PY - 2008/2

Y1 - 2008/2

N2 - The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

AB - The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

KW - TS-1

KW - Ti-MWW

KW - epoxidation

KW - functionalized olefin

UR - https://www.scopus.com/pages/publications/40949113603

U2 - 10.1016/S1872-2067(08)60018-2

DO - 10.1016/S1872-2067(08)60018-2

M3 - 文章

AN - SCOPUS:40949113603

SN - 1872-2067

VL - 29

SP - 102

EP - 104

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 2

ER -

Epoxidation of Various Functionalized Olefins by a Ti-MWW/H₂O₂ Catalytic System

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Keywords

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