Enhanced immobilization of lead, cadmium, and arsenic in smelter-contaminated soil by sulfidated zero-valent iron

Soils contaminated with multiple heavy metal(loid)s (HMs) such as lead (Pb), cadmium (Cd), and arsenic (As) are of great concern in many countries. In this study, taking three lead-zinc smelter soils, the performance of sulfidated zero-valent iron (S-ZVI) toward Pb, Cd, and As immobilization was systemically investigated. Results showed that more than 88% of water-extractable Pb and Cd could be immobilized and transformed into reducible, oxidizable, and/or reducible forms by S-ZVI within 3 h, whereas only 3–56% of them could be immobilized by unsulfidated ZVI even after 72 h. Meanwhile, the phytoavailability of the tested HMs could be effectively reduced by 79% after S-ZVI amendment. More importantly, anoxic/oxic incubation tests revealed that the dissolved concentrations of HMs were much lower in S-ZVI-treated soils than in the untreated or unmodified ZVI-treated soils. Speciation analysis further suggested that unmodified ZVI seemed to reduce the long-term soil stability by changing the residual HMs species to mild-acid soluble and/or reducible ones. In contrast, S-ZVI could effectively alleviate the remobilization of HMs under the changeover of soil redox environments. All these findings indicate that S-ZVI may be a promising amendment for the immobilization of Pb, Cd, and As in smelter-contaminated soil.