Enhanced catalytic oxidation performance of F-Ti-MWW through the synergistic effect of anion and cation

Xiangqing Fang; Le Sun; Longfei Lin; Lizhi Wu; Yueming Liu

doi:10.1016/j.catcom.2017.04.007

Enhanced catalytic oxidation performance of F-Ti-MWW through the synergistic effect of anion and cation

Xiangqing Fang, Le Sun, Longfei Lin, Lizhi Wu, Yueming Liu

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The catalytic performance of F-Ti-MWW towards the epoxidation of 1-hexene with H₂O₂ was enhanced dramatically, which was attributed to the synergistic effects between anion and cation in the inorganic salt. The negative influence of F⁻ in the SiO_4/2F⁻ units was eliminated selectively by convenient anion-exchange and cation-neutralize with various alkali chlorides.

Original language	English
Pages (from-to)	54-57
Number of pages	4
Journal	Catalysis Communications
Volume	96
DOIs	https://doi.org/10.1016/j.catcom.2017.04.007
State	Published - 2017

Keywords

Anion-exchange
Cation-neutralize
F-Ti-MWW
SiOF units

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10.1016/j.catcom.2017.04.007

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title = "Enhanced catalytic oxidation performance of F-Ti-MWW through the synergistic effect of anion and cation",

abstract = "The catalytic performance of F-Ti-MWW towards the epoxidation of 1-hexene with H2O2 was enhanced dramatically, which was attributed to the synergistic effects between anion and cation in the inorganic salt. The negative influence of F− in the SiO4/2F− units was eliminated selectively by convenient anion-exchange and cation-neutralize with various alkali chlorides.",

keywords = "Anion-exchange, Cation-neutralize, F-Ti-MWW, SiOF units",

author = "Xiangqing Fang and Le Sun and Longfei Lin and Lizhi Wu and Yueming Liu",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

doi = "10.1016/j.catcom.2017.04.007",

language = "英语",

volume = "96",

pages = "54--57",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

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T1 - Enhanced catalytic oxidation performance of F-Ti-MWW through the synergistic effect of anion and cation

AU - Fang, Xiangqing

AU - Sun, Le

AU - Lin, Longfei

AU - Wu, Lizhi

AU - Liu, Yueming

PY - 2017

Y1 - 2017

N2 - The catalytic performance of F-Ti-MWW towards the epoxidation of 1-hexene with H2O2 was enhanced dramatically, which was attributed to the synergistic effects between anion and cation in the inorganic salt. The negative influence of F− in the SiO4/2F− units was eliminated selectively by convenient anion-exchange and cation-neutralize with various alkali chlorides.

AB - The catalytic performance of F-Ti-MWW towards the epoxidation of 1-hexene with H2O2 was enhanced dramatically, which was attributed to the synergistic effects between anion and cation in the inorganic salt. The negative influence of F− in the SiO4/2F− units was eliminated selectively by convenient anion-exchange and cation-neutralize with various alkali chlorides.

KW - Anion-exchange

KW - Cation-neutralize

KW - F-Ti-MWW

KW - SiOF units

UR - https://www.scopus.com/pages/publications/85017190998

U2 - 10.1016/j.catcom.2017.04.007

DO - 10.1016/j.catcom.2017.04.007

M3 - 文章

AN - SCOPUS:85017190998

SN - 1566-7367

VL - 96

SP - 54

EP - 57

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Enhanced catalytic oxidation performance of F-Ti-MWW through the synergistic effect of anion and cation

Abstract

Keywords

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