Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions

Xiujuan Deng; Shuo Zhang; Binshen Wang; Yuning Wang; Haihong Wu; Yueming Liu; Mingyuan He

doi:10.1039/c3cc43372b

Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions

Xiujuan Deng
, Shuo Zhang
, Binshen Wang
, Yuning Wang
, Haihong Wu
, Yueming Liu^*
, Mingyuan He

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A typical volcano-shaped curve has been found in heterogeneous catalytic systems containing titanosilicates for the first time. A new reactive intermediate with double H-bonds is proposed. Systematic results clearly evidence another H-bond formed between the high-electronegativity atom of the H-bond acceptor and the H_end atom of Ti–O_α–O_β–H_end.

Original language	English
Pages (from-to)	7504-7506
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	68
DOIs	https://doi.org/10.1039/c3cc43372b
State	Published - 30 Jul 2013

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title = "Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions",

abstract = "A typical volcano-shaped curve has been found in heterogeneous catalytic systems containing titanosilicates for the first time. A new reactive intermediate with double H-bonds is proposed. Systematic results clearly evidence another H-bond formed between the high-electronegativity atom of the H-bond acceptor and the Hend atom of Ti–Oα–Oβ–Hend.",

author = "Xiujuan Deng and Shuo Zhang and Binshen Wang and Yuning Wang and Haihong Wu and Yueming Liu and Mingyuan He",

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T1 - Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions

AU - Deng, Xiujuan

AU - Zhang, Shuo

AU - Wang, Binshen

AU - Wang, Yuning

AU - Wu, Haihong

AU - Liu, Yueming

AU - He, Mingyuan

PY - 2013/7/30

Y1 - 2013/7/30

N2 - A typical volcano-shaped curve has been found in heterogeneous catalytic systems containing titanosilicates for the first time. A new reactive intermediate with double H-bonds is proposed. Systematic results clearly evidence another H-bond formed between the high-electronegativity atom of the H-bond acceptor and the Hend atom of Ti–Oα–Oβ–Hend.

AB - A typical volcano-shaped curve has been found in heterogeneous catalytic systems containing titanosilicates for the first time. A new reactive intermediate with double H-bonds is proposed. Systematic results clearly evidence another H-bond formed between the high-electronegativity atom of the H-bond acceptor and the Hend atom of Ti–Oα–Oβ–Hend.

UR - https://www.scopus.com/pages/publications/84881106914

U2 - 10.1039/c3cc43372b

DO - 10.1039/c3cc43372b

M3 - 文章

AN - SCOPUS:84881106914

SN - 1359-7345

VL - 49

SP - 7504

EP - 7506

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -

Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions

Abstract

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