TY - JOUR
T1 - Engineered diatomic catalyst empowered electro-Fenton processes for advanced water purification
AU - Sun, Wenxin
AU - Zou, Hua
AU - Liu, Guoshuai
AU - Guan, Xiaohong
AU - Wang, Shaobin
AU - Duan, Xiaoguang
N1 - Publisher Copyright:
© 2024 The Royal Society of Chemistry.
PY - 2024/9/12
Y1 - 2024/9/12
N2 - The heterogeneous electro-Fenton (EF) process has attracted tremendous interest as a promising advanced oxidation reaction to treat refractory organic contaminants in water. However, its practical application has been limited by unsatisfactory catalyst performance. Atomically dispersed metal catalysts are appealing for EF systems due to their high atomic utilization, intrinsic activity, and selectivity. In this review, we introduce the latest advances in metal-based single atom catalysts (SACs) for coordinating multiple oxygen reduction pathways in EF. First, we present a comprehensive summary of rational SAC design for selectively converting O2 to H2O2 and ultimately to ˙OH in successive reactions, as well as the associated mechanisms. Subsequently, we delve into the design and synthesis principles of diatomic catalysts (DACs), highlighting their collaborative functions to direct selective O2 conversion to ˙OH. Finally, we conclude the review by discussing current challenges and further directions for the intelligent design of electrodes and reactors coupled with well-defined DACs for EF-based purification technologies.
AB - The heterogeneous electro-Fenton (EF) process has attracted tremendous interest as a promising advanced oxidation reaction to treat refractory organic contaminants in water. However, its practical application has been limited by unsatisfactory catalyst performance. Atomically dispersed metal catalysts are appealing for EF systems due to their high atomic utilization, intrinsic activity, and selectivity. In this review, we introduce the latest advances in metal-based single atom catalysts (SACs) for coordinating multiple oxygen reduction pathways in EF. First, we present a comprehensive summary of rational SAC design for selectively converting O2 to H2O2 and ultimately to ˙OH in successive reactions, as well as the associated mechanisms. Subsequently, we delve into the design and synthesis principles of diatomic catalysts (DACs), highlighting their collaborative functions to direct selective O2 conversion to ˙OH. Finally, we conclude the review by discussing current challenges and further directions for the intelligent design of electrodes and reactors coupled with well-defined DACs for EF-based purification technologies.
UR - https://www.scopus.com/pages/publications/85204675188
U2 - 10.1039/d4ta04567j
DO - 10.1039/d4ta04567j
M3 - 文献综述
AN - SCOPUS:85204675188
SN - 2050-7488
VL - 12
SP - 26439
EP - 26456
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
IS - 39
ER -
