Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis

Sheng Cai Zheng; Min Zhang; Xiao Ming Zhao

doi:10.1002/chem.201402388

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO₂ under iridium catalysis

Sheng Cai Zheng
, Min Zhang
, Xiao Ming Zhao^*

^*Corresponding author for this work

Tongji University

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO₂ in the presence of an Ir complex and K₃PO₄ was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO₂ in this transformation is discussed as well.

Original language	English
Pages (from-to)	7216-7221
Number of pages	6
Journal	Chemistry - A European Journal
Volume	20
Issue number	24
DOIs	https://doi.org/10.1002/chem.201402388
State	Published - 10 Jun 2014
Externally published	Yes

Keywords

allylcarbamates
carbon dioxide
domino reactions
enantioselectivity
iridium

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10.1002/chem.201402388

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title = "Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis",

abstract = "Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93\% ee. The role of CO2 in this transformation is discussed as well.",

keywords = "allylcarbamates, carbon dioxide, domino reactions, enantioselectivity, iridium",

author = "Zheng, \{Sheng Cai\} and Min Zhang and Zhao, \{Xiao Ming\}",

year = "2014",

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doi = "10.1002/chem.201402388",

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volume = "20",

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journal = "Chemistry - A European Journal",

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TY - JOUR

T1 - Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis

AU - Zheng, Sheng Cai

AU - Zhang, Min

AU - Zhao, Xiao Ming

PY - 2014/6/10

Y1 - 2014/6/10

N2 - Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO2 in this transformation is discussed as well.

AB - Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO2 in this transformation is discussed as well.

KW - allylcarbamates

KW - carbon dioxide

KW - domino reactions

KW - enantioselectivity

KW - iridium

UR - https://www.scopus.com/pages/publications/84902139420

U2 - 10.1002/chem.201402388

DO - 10.1002/chem.201402388

M3 - 文章

AN - SCOPUS:84902139420

SN - 0947-6539

VL - 20

SP - 7216

EP - 7221

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 24

ER -

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO₂ under iridium catalysis

Abstract

Keywords

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